Comparison of properties of conducting TCNQ salts with 1,4-bis[1-(4--r-pyridinio)]butane and trans-2-butene dications | |
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學年 | 79 |
學期 | 2 |
出版(發表)日期 | 1991-05-15 |
作品名稱 | Comparison of properties of conducting TCNQ salts with 1,4-bis[1-(4--r-pyridinio)]butane and trans-2-butene dications |
作品名稱(其他語言) | |
著者 | 余良杰; Yu, L. J. |
單位 | 淡江大學化學學系 |
出版者 | Elsevier |
著錄名稱、卷期、頁數 | Synthetic metals 42(1-2), pp.1751-1756 |
摘要 | Conducting TCNQ salts are prepared with dications consisting of butyl and trans-2-butenyl as the central linkages and various 4-substituted pyridinium as the charged end groups. Conductivities are comparable and of low values (10−4 − 10−2 S/cm) for the salts having H, t-butyl and benzyl as the substituents of pyridine irrespective of central linkages. For the salts with 4-methyl and 4-ethyl as the substituents of pyridine, the conductivities are 4 orders of magnitude higher for butyl linkage. UV-VIS-Near IR and IR spectra of these salts are presented. The variation of conductivity is explained in terms of dication structures. |
關鍵字 | |
語言 | en |
ISSN | 0379-6779 |
期刊性質 | 國內 |
收錄於 | |
產學合作 | |
通訊作者 | |
審稿制度 | 否 |
國別 | TWN |
公開徵稿 | |
出版型式 | ,電子版 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/24882 ) |