Ferroelectric liquid crystals consisted of butyl lactate and 3-naphthyl-propenoic acid derivatives | |
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學年 | 86 |
學期 | 1 |
出版(發表)日期 | 1998-01-01 |
作品名稱 | Ferroelectric liquid crystals consisted of butyl lactate and 3-naphthyl-propenoic acid derivatives |
作品名稱(其他語言) | |
著者 | Wang, T. Y.; Yu, Liang-jye |
單位 | 淡江大學化學學系 |
出版者 | Taylor & Francis |
著錄名稱、卷期、頁數 | Ferroelectrics 212(1), pp.379-386 |
摘要 | 3-(6-alkyloxy-2-naphthyl)propenoic acids were connected by phydroxybenzoic acid to L-(-)-ethyl lactate and L-(-)-butyl lactate, CnONPBLC2 and CnONPBLC4, respectively. CnONPBBLC4 series was obtained with one p-hydroxy benzoic acid unit more as the core. CnONPBLC2, n=6, 8, 10 and 12, exhibited enantiotropic smectic A (SA) phase in the range of 60 to 120 [ddot]C. Monotropic chiral smectic C (Sc*) phases were observed for n=10 and 12. CnONPBLC4 series exhibited enantiotropic SA phases. Sc* phases were observed for n=8 and 9 monotropically and n=12 and 14 enantiotropically. CnONPBBLC4 exhibited enantiotropic Sc* and SA phases. The transition temperatures for crystal to Sc*, Sc* to SA and SA to Iso were 80, 170 and 220 [ddot]C, respectively. Extremely wide temperature range for Sc* phase was observed. The values of Ps and tilting angle of C12ONPBLC4 were 54 nC/cm2 and 22 degrees, respectively, at 30 [ddot]C below the SA-Sc* transition. |
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語言 | en |
ISSN | 0015-0193 |
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產學合作 | |
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相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/24978 ) |