Electrochemiacl doping of tetraethylammonium on C60 film
學年 83
學期 2
出版（發表）日期 1995-03-15
作品名稱 Electrochemiacl doping of tetraethylammonium on C60 film
作品名稱（其他語言） 以電化學方法植入Tetraethylammonium在C60薄膜中
著者 王文竹; Wang, Wen-jwu; Chiu, Hau-shy; 余良杰; Yu, Liang-jye; 王伯昌; Wang, Bo-cheng
單位 淡江大學化學學系
出版者 Elsevier
著錄名稱、卷期、頁數 Synthetic metals 70(1-3), pp.1439-1442
摘要 The electrochemical behavior of C60 films, which was prepared on electrode by solution casting method, during redox processes in acetonitrile solution containing tetraethylammonium perchlorate as supporting electrolyte was examined by means of cyclic voltammetry (CV) and electrochemical quartz crystal microbalance (EQCM) technique. In the CV behavior, there are four reductive waves at R1=-1.17 V, R2=-1.25 V, R3=-1.40 V and R4=-1.55 V vsFc/Fc+ which are corresponding to C60(TEA+)/C60-(TEA+), C60/C60, C60 (TEA+)/C60−2 reactions, respectively. There are four reoxidative waves at 04=-1.29 V, 03=-1.06 V, 02=-0.76 V and 01=-0.55 V vs Fc/Fc+ which are corresponding to C60−2 deposition on film, C60-/C60, and C60−2(TEA+)2/C60-(TEA+)/C60(TEA-), respectively. The dissolution/ depositive of C60−n(n=1,2) and doping / dedoping of TEA+ on C60 films at different potential are investigated and approved by EQCM studied.
關鍵字
語言 en
ISSN 0379-6779
期刊性質 國內
收錄於
產學合作
通訊作者
審稿制度 否
國別 TWN
公開徵稿
出版型式 ,電子版
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