| A new curing agent for self-curable system of aqueous-based PU dispersion | |
|---|---|
| 學年 | 95 |
| 學期 | 2 |
| 出版（發表）日期 | 2007-04-01 |
| 作品名稱 | A new curing agent for self-curable system of aqueous-based PU dispersion |
| 作品名稱（其他語言） | |
| 著者 | Wang, Shih-Chieh; Chen, Po-Cheng; Yeh, Jen-taut; Chen, Kan-nan |
| 單位 | 淡江大學化學學系 |
| 出版者 | Elsevier |
| 著錄名稱、卷期、頁數 | Reactive and Functional Polymers 67(4), pp.299-311 |
| 摘要 | Anionic aqueous-based polyurethane (PU) dispersion consists of carboxyl group that served as an internal emulsifier stabilizing aqueous PU dispersion and also a reactive site toward curing agent. A model reaction of a mono-azetidine-containing compound and trimethylacetic acid (TMAA) demonstrated that an amino ester bond formation between azetidine and carboxylic acid. A di-azetidine containing compound (HDDA–AZT) was prepared and served as a curing agent, which was synthesized by a Michael addition reaction of azetidine (AZT) to hexanediol diacrylate (HDDA). Anionic aqueous PU dispersion was treated with HDDA–AZT as a latent curing agent and becoming a self-curable aqueous PU system. A cross-linked PU resin was obtained from this self-curing PU system on drying at ambient temperature. The performance properties of these self-cured PU resins proved that cross-linking behaviors with this new curing agent, HDDA–AZT. |
| 關鍵字 | Azetidine;Self-curing;Ring-opening;Aqueous-based PU |
| 語言 | en |
| ISSN | 1381-5148 |
| 期刊性質 | 國外 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | NLD |
| 公開徵稿 | |
| 出版型式 | ,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/19543 ) |
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