| 標題：Introduction of covalently bonded phosphorus into aqueous-based polyurethane system via postcuring reaction |
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| 學年 | 88 |
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| 學期 | 1 |
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| 出版（發表）日期 | 1999/12/05 |
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| 作品名稱 | Introduction of covalently bonded phosphorus into aqueous-based polyurethane system via postcuring reaction |
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| 作品名稱（其他語言） | |
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| 著者 | Wang, Ta-zen; Chen, Kan-nan |
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| 單位 | 淡江大學化學學系 |
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| 出版者 | John Wiley & Sons |
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| 著錄名稱、卷期、頁數 | Journal of Applied Polymer Science 74(10), pp.2499-2509 |
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| 摘要 | Anionic aqueous-based polyurethane (PU) dispersions were derived from a water dispersion process of carboxylic groups containing PU prepolymers together with a neutralization and a chain extension. These PU prepolymers were prepared from a conventional polyaddition of isophorone diisocyanate, polypropylene glycol-1000, and dimethylolpropanic acid. A covalently bonded phosphorus was introduced into PU by a phosporus-containing curing agent. A series of phosphorus and multi-aziridinyl groups containing curing agents were synthesized for this purpose. Each of them served in a dual-function capacity as a postcuring agent for the anionic aqueous-based PU system. The resulting postcured PU exhibited improvements in its mechanical, physical, and thermal properties; furthermore, postcured PU synergistic flame inhibition was also observed due to the presence of nitrogen and phosphorus content in the process. |
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| 關鍵字 | |
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| 語言 | 英文(美國) |
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| ISSN | 0021-8995 |
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| 期刊性質 | 國外 |
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| 收錄於 | |
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| 產學合作 | |
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| 通訊作者 | |
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| 審稿制度 | 否 |
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| 國別 | 美國 |
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| 公開徵稿 | |
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| 出版型式 | ,紙本 |
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| 相關連結 | |
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| SDGs | |
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