A cross self-curing system for an aqueous-based PU hybrid | |
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學年 | 93 |
學期 | 2 |
出版(發表)日期 | 2005-07-15 |
作品名稱 | A cross self-curing system for an aqueous-based PU hybrid |
作品名稱(其他語言) | |
著者 | Lai, Jian-zei; Chen, Pao-jan; Yeh, Jen-taut; Chen, Kan-nan |
單位 | 淡江大學化學學系 |
出版者 | John Wiley & Sons |
著錄名稱、卷期、頁數 | Journal of Applied Polymer Science 97(2), pp.550-558 |
摘要 | Isocyanate (NCO)-terminated polyurethane (PU) prepolymer comprises carboxylic acid, which is obtained from a conventional PU preparation procedure. Aziridine-terminated PU oligomer is prepared by an addition reaction of aziridine to NCO-terminated PU prepolymer after it is neutralized with triethylamine. This PU oligomer is then dispersed with water and becomes a single-component self-curable aqueous-based PU dispersion (PU-AZ). PU carboxyl groups are not only the ionic centers stabilizing the aqueous polymer dispersion, but also serve as PU curing sites toward the curing reaction with its aziridine terminal groups on drying. This self-curable PU-AZ dispersion is miscible and compatible with other carboxyl groups containing aqueous-based PU dispersion in any ratio, which results in a cross self-cured PU hybrid formation on drying. This cross self-cured PU hybridization process allows property modification and the curing of PU simultaneously without the addition of any external curing agent. |
關鍵字 | self-curing; PU hybrid; aziridine |
語言 | |
ISSN | 0021-8995 |
期刊性質 | 國外 |
收錄於 | SCI |
產學合作 | |
通訊作者 | |
審稿制度 | |
國別 | |
公開徵稿 | |
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相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/19533 ) |