教師資料查詢 | 類別: 期刊論文 | 教師: 陳幹男CHEN KAN-NAN (瀏覽個人網頁)

標題:Polymer hybrids from self-emulsified PU anionomer and water-reducible acrylate copolymer via a postcuring reaction
學年92
學期1
出版(發表)日期2003/12/20
作品名稱Polymer hybrids from self-emulsified PU anionomer and water-reducible acrylate copolymer via a postcuring reaction
作品名稱(其他語言)
著者Lai, Jian-zei; Ling, Hao-Jan; Chen, Guan-nan; Yeh, Jen-taut; Chen, Kan-nan
單位淡江大學化學學系
出版者John Wiley & Sons
著錄名稱、卷期、頁數Journal of Applied Polymer Science 90(13), pp.3578-3587
摘要Water-reducible acrylate copolymer is obtained from a free-radical copolymerization of n-butyl acrylate, acrylic acid, and methacrylic acid. Self-emulsified aqueous-based polyurethane (PU) anionomer is prepared by the conventional method. The latent curing agents (di- and triaziridinyl compounds, HDDA-AZ and TMPTA-AZ) are synthesized from the reaction of aziridine with hexandiol diacrylate and trimethylolpropane triacrylate, respectively. These two polymers and the latent curing agent are miscible in each other and become a single component and self-curable polymer dispersion. The carboxyl ions of polymers not only stabilize the aqueous polymer dispersions but also serve the curing site toward latent curing agent in the drying process. These two polymers blend with a curing agent, which results in new polymer hybrid formation. These polymer hybrids have the improvements on performance properties and the cost/performance benefits.
關鍵字
語言英文(美國)
ISSN0021-8995
期刊性質國外
收錄於
產學合作
通訊作者
審稿制度
國別美國
公開徵稿
出版型式,電子版
相關連結
SDGs
Google+ 推薦功能,讓全世界都能看到您的推薦!