| The study of some modified polyurethanes(IV) ; curing of polyester ase polyurethane coatings with ultraviolet irradiation | |
|---|---|
| 學年 | 75 |
| 學期 | 1 |
| 出版（發表）日期 | 1986-12-01 |
| 作品名稱 | The study of some modified polyurethanes(IV) ; curing of polyester ase polyurethane coatings with ultraviolet irradiation |
| 作品名稱（其他語言） | 改良式聚胺基甲酸乙酯研究(IV)紫外光硬化之聚胺基甲酸乙酯塗料 |
| 著者 | 陳幹男; Chen, Kan-nan; 王生文; Sheng-Wen Wang |
| 單位 | 淡江大學化學學系 |
| 出版者 | 中國化學會 |
| 著錄名稱、卷期、頁數 | 化學 44(4)，頁143-151 |
| 摘要 | Ultraviolet curable polyure thane oligomers were prepared from toluene diiocyanates and polyester polyols based polyurethane prepolymers and methacrylates were the terminal groups. Trimethylolpropane trimethacrylate (TMPTA) was added into the corresponding polyurethane methacrylate oligo-mers as a reactive diluent. Benzophenone or benzoin ethylether was served as a photosensitizer or photoinitiator, respectively. UV spectra of UV curable PU system could be a reference for the selection of photosensitizers (or photoinitiators). The rate of disappearance on double bonds of methacr-ylates terminated PU could be detected by FT-IR (on 1635 cm^(-1)). The properties (e.g. gel contents, pencil hardness, tensile strength, impact strength and thermogravimetry) of the cured film with various UV irradiation time were investigated. |
| 關鍵字 | |
| 語言 | zh_TW |
| ISSN | 0441-3768 |
| 期刊性質 | 國內 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25373 ) |
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