Properties of conducting 7,7,8,8-tetracyano-p-quinodimethane salts with 1, n-bis[1-(.gamma.-picolinio)]alkane dication homologues
學年 76
學期 2
出版（發表）日期 1988-07-01
作品名稱 Properties of conducting 7,7,8,8-tetracyano-p-quinodimethane salts with 1, n-bis[1-(.gamma.-picolinio)]alkane dication homologues
作品名稱（其他語言）
著者 余良杰; Yu, L. J.; Lang, F. C.; 李榮熹; Lee, J. S.
單位 淡江大學化學學系
出版者 Washington: American Chemical Society (ACS)
著錄名稱、卷期、頁數 Journal of physical chemistry 92(15), pp.4543-4546
摘要 1,n-Bis[ 1-(y-picolinio)]alkane(TCNQ), salts are nonstoichiometric with m varying from 3.4 to 4.7 for n = 2-7. The conductivity (compressed pellet, four-probe method, in the temperature range 23C-310 K) varies with the alkyl chain length of the dications, the highest being 2 S cm-I, for n = 4 and m = 4.6, with the lowest activation energy (0.033 eV). FT-IR and electronic absorption spectra are presented and discussed. On the basis of the results observed, a possible structure is proposed for these homologous salts.
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語言 en
ISSN 1520-6106
期刊性質 國外
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產學合作
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審稿制度
國別 USA
公開徵稿
出版型式 紙本
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