UV-curable Fluorine-containing IPN System for Fabric Water-repellency Treatment
學年 96
學期 1
出版(發表)日期 2008-01-01
作品名稱 UV-curable Fluorine-containing IPN System for Fabric Water-repellency Treatment
著者 Chen, Wei-hung; Yeh, Jen-taut; Huang, Chi-yuan; Chen, Kan-nan
單位 淡江大學化學學系
出版者 Berlin: Walter de Gruyter GmbH & Co. KG
著錄名稱、卷期、頁數 Journal of polymer engineering 28(8), pp.517-534
摘要 A fluorinated acrylate monomer, 2, 2, 3, 3, 4, 4, 5, 5-octafluoropentyl-methacrylate (OFPMA) was synthesized from a reaction between methacrylol chloride and fluorine containing alcohol (2, 2, 3, 3, 4, 4, 5, 5-octafluoropentanol, OFPOH). The fluorine containing acrylate co-polymer (OFPMA-MA) was prepared by a solution copolymerization of OFPMA and methyl acrylate (MA). An UV-curable fluorine containing inter-penetrating polymeric network (IPN) system was formulated by mixing OFPMA-MA co-polymer with UV curable epoxy acrylate oligomer. The UV-curable IPN system was coated on fabric surface and cured by UV radiation process. Upon UV curing, the highly cross-linked polymer anchored into fabric fibers that enhance the washing durability of treated fabric. The fluorinated acrylate monomer (OFPMA) and UV-curable epoxyacrylate oligomer (UV-epoxy) were characterized by FT-IR and NMR. The water repellency of the treated fabric surface was exhibited that related to its fluorine content of UV-cured IPN system. The fluorine contents of treated fabrics after washing were identified by SEM-EDS and their surface properties were proved by the contact angle measurements and Kawabata fabric evolution system (KES-FB).
關鍵字 Ester polymer; Experimental study; Coated fabric; Ethylene terephthalate polymer; Nylon; Synthetic fiber; Coating material; Hydrophobicity; Acrylate copolymer; Photochemical copolymerization; Radical copolymerization; Surface properties; Ultraviolet radiation; Methyl acrylate copolymer; Fluorine containing copolymer; Solution copolymerization; Methacrylate copolymer; Woven material; Interpenetrating polymer network
語言 en
ISSN 0334-6447
期刊性質 國外
收錄於 SCI
通訊作者 Chen, Kan-nan
國別 DEU
出版型式 紙本

機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/50780 )