Observation of self-ion-molecule reactions during collisionally activated dissociation in an ion-trap mass spectrometer
學年 92
學期 2
出版(發表)日期 2004-04-01
作品名稱 Observation of self-ion-molecule reactions during collisionally activated dissociation in an ion-trap mass spectrometer
作品名稱(其他語言)
著者 Wu, Hui-fen; Wu, Mon-tin; Chen, Chien-hung
單位 淡江大學化學學系
出版者 Chichester: John Wiley & Sons Ltd.
著錄名稱、卷期、頁數 Journal of mass spectrometry 39(4), pp.396-401
摘要 This paper describes the formation of protonated molecules ([M + H]+) and adduct ions by self-ion-molecule reactions (SIMR) during collisionally activated decomposition (CAD) of methyne addition ions ([M + CH]+) produced from chemical ionization (CI) or SIMR in both an external and internal source ion-trap mass spectrometer (ITMS). The CAD results for the methyne addition ions of dopamine produced from both SIMR and dimethyl ether CI undertaken in the external and internal source ITMS were compared in order to prove the occurrence of SIMR during CAD processes. Compared with the external source ITMS, the internal source ITMS is much more easily applicable to this type of reaction owing to the large population of neutral analytes present in the trap.
關鍵字 ion–molecule reactions; ion trap; dopamine
語言 en
ISSN 1076-5174 1096-9888
期刊性質 國外
收錄於
產學合作
通訊作者
審稿制度
國別 GBR
公開徵稿
出版型式 紙本
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