期刊論文
| 學年 | 114 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2026-01-01 |
| 作品名稱 | Isomeric halide engineering of self-assembled hole-selective layers for efficient indoor perovskite photovoltaics |
| 作品名稱（其他語言） | |
| 著者 | Zhong-En Shi; Yi-Ting Hong; Cheng-Chieh Lu; Po-Cheng Shih; Shih-I Lu; Hsiao-Chi Hsieh; Sie-Rong Li; Yu-Che Lin; Zheng-Xuan Cai; Yan-Duo Lin; Chih-Ping Chen |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Chemical Engineering Journal 527, p.171787 |
| 摘要 | Self-assembled hole-selective layers (HSLs) have emerged as a versatile and effective approach for engineering the interfaces of electronic and optoelectronic devices. To achieve precise control over the molecular organization and functionality of HSLs, we designed and synthesized a series of carbazole-based donor–acceptor (D–A) molecules—L-H, L-Cl, Bsingle bondH, and B-Cl—with and without chlorine incorporation. These molecules were developed for use as HSL in perovskite solar cells (PSCs). These multifunctional HSL feature a donor–acceptor framework that facilitates hole transport, while a benzoic acid anchoring group ensures robust substrate binding and promotes face-on π–π stacking parallel to the transparent conductive oxide surface. Compared with their non-chlorinated analogues (L-H and Bsingle bondH), the chlorinated derivatives (L-Cl and Bsingle bondCl) exhibit stronger dipole moments and enhance the HSL/perovskite interface. The L- and B-series HSLs effectively passivate perovskite defects, optimize interfacial energy alignment, and improve carrier transport dynamics. Notably, the optimized L-Cl-based Cs0.18FA0.82Pb(I0.8Br0.2)3 p–i–n PSC achieves a remarkable power conversion efficiency (PCE) exceeding 41 % under indoor lighting (WLED, 1000 lx). Moreover, L-Cl-based devices demonstrate outstanding environmental stability, retaining nearly unchanged efficiency after 770 h storage under ambient conditions (25 °C, 50 % relative humidity), without encapsulation. These results demonstrate that D–A-type molecular interface engineering effectively enhances defect passivation and interfacial contact, offering a promising route toward high-efficiency, long-term stable PSCs. |
| 關鍵字 | Carbazole derivatives; Chlorine-substituted small molecules; Hole-transporting materials; Perovskite solar cells; Indoor photovoltaics |
| 語言 | en |
| ISSN | 1385-8947; 1873-3212 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | NLD |
| 公開徵稿 | |
| 出版型式 | ,電子版,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/129421 ) |