期刊論文
| 學年 | 110 |
|---|---|
| 學期 | 2 |
| 出版（發表）日期 | 2022-07-30 |
| 作品名稱 | Differential Surface Partitioning for An Ultrasensitive Solid-State SERS Sensor and Its Application to Food Colorant Analysis |
| 作品名稱（其他語言） | |
| 著者 | Yu-San Chien; Chia-Wen Chang; Chia-Chi Huang |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Food Chemistry, 132415 |
| 摘要 | Solid-state SERS sensors are desirable point-of-care tools due to their portability. However, the level of SERS sensitivity achieved in liquid phase is rarely duplicated in the solid phase. We report herein the fabrication of a SERS sensor using alumina beads as the solid support and demonstrate its high SERS sensitivity with the model analyte 4-aminophenyl disulfide (4-APDS). The key to sensitivity is a hydrophilic-hydrophobic surface gradient constructed by sequentially coating with the surfactant cetyltrimethylammonium bromide and fluorous 1H,1H,2H,2H-perfluorooctyltriethoxysilane. The surface gradient, together with chloride etching, allows the detection of 4-APDS at the low concentration of 10-15 M. The practicality of the sensor beads is evidenced by successfully tracking the SERS fingerprints of five food colorant standards in the SERS spectra of a popular candy product. These SERS sensor beads are easy to prepare, convenient to use, and highly responsive as a SERS platform for the analysis of colorants. |
| 關鍵字 | SERS;hydrophobic;oleophobic;4-aminophenyl disulfide;food colorants |
| 語言 | en_US |
| ISSN | 0308-8146 |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | Chia-Chi Huang |
| 審稿制度 | 是 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/122129 ) |