期刊論文
| 學年 | 97 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2009-01-01 |
| 作品名稱 | Thermochemical behavior of metallic citrate precursors for the production of pure LaAlO3 |
| 作品名稱（其他語言） | |
| 著者 | 余宣賦; Yu, Hsuan-fu; Wang, Juy; Wang, Shuen-shian; Kuo, Yu-man |
| 單位 | 淡江大學化學工程與材料工程學系 |
| 出版者 | Kidlington: Pergamon |
| 著錄名稱、卷期、頁數 | Journal of Physics and Chemistry of Solids 70(1), pp.218-223 |
| 摘要 | Pure LaAlO3 nanoparticles were synthesized, using a citrate-precursor technique. La(NO3)3, Al(NO3)3, and C3H4(OH)(COOH)3, in a molar ratio of 1:1:4.5, were dissolved in deionized water. The pH of the aqueous solution was adjusted using NH4OH. After drying, the citrate precursors were charred at 350 °C, followed by calcination at different temperatures. The thermochemical behavior of the charred citrate precursor to form LaAlO3 was investigated using X-ray diffractometry, infrared spectroscopy, thermogravimetric analysis, and differential thermal analysis. While the charred specimen obtained at pH=2 (without NH4OH addition) was composed of LaAl(OOCH2)3, the charred specimens obtained at pH>2 were composed of LaAlO3−x−y(CO3)x(OH)2y. All these metallic salts were decomposed at temperatures between 600 and 780 °C to form crystalline LaAlO3 but calcining the specimens in air at 800 °C were required to remove all residual chars to produce pure LaAlO3. At 900 °C, the citrate-derived particles obtained at pH>2 were composed of LaAlO3 crystallites with an average size of 30 nm. |
| 關鍵字 | A. Ceramics; B. Chemical synthesis; C. Infrared spectroscopy; C. X-ray diffraction; D. Phase transitions |
| 語言 | en |
| ISSN | 0022-3697 |
| 期刊性質 | 國外 |
| 收錄於 | SCI EI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | |
| 國別 | GBR |
| 公開徵稿 | |
| 出版型式 | |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/44186 ) |