標題:The effect of Tween-20 additive on the morphology and performance of PVDF membranes |
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學年 | 103 |
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學期 | 1 |
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出版(發表)日期 | 2014/09/15 |
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作品名稱 | The effect of Tween-20 additive on the morphology and performance of PVDF membranes |
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作品名稱(其他語言) | |
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著者 | Hsu-Hsien Chang; Sheng-Chang Chen; Dar-Jong Lin; Liao-Ping Cheng |
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單位 | |
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出版者 | |
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著錄名稱、卷期、頁數 | Journal of Membrane Science 466, p.302-312 |
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摘要 | The effects of additive, Tween-20, on the morphology and ultra-filtration performance of the PVDF membranes formed by isothermal immersion precipitation from the Tween-20/water/TEP/PVDF system were investigated. High resolution FESEM imaging indicates that the membranes׳ bulk constituted of interlinked crystalline particles, whose shapes change from more sheaf-like to more stick-like as larger amounts of Tween-20 were initially added into the dope. Introduction of Tween-20 caused formation of nano-pores on the top surfaces of the membranes and micron-sized columnar voids underneath the top skin layer. Some small amounts of Tween-20 may reside in the formed membrane if the nascent membrane has not been carefully washed. Presence of Tween-20 in the membrane was analyzed by water contact angle measurements, Fourier Transform Infrared-Attenuated total reflection spectroscopy (FTIR-ATR), Nuclear Magnetic Resonance (NMR), and X-ray Photoelectron Spectroscopy (XPS). Furthermore, water flux and blue dextran filtration experiments were carried out to illustrate the potential applications of the membranes in fine separation processes. |
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關鍵字 | |
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語言 | 英文(美國) |
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ISSN | |
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期刊性質 | 國外 |
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收錄於 | |
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產學合作 | |
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通訊作者 | |
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審稿制度 | 否 |
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國別 | 中華民國 |
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公開徵稿 | |
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出版型式 | ,電子版 |
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相關連結 | |
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