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標題:Synthesis, characterization, and reactivity of dinitrosyl iron complexes stabilized by N-heterocyclic carbenes
學年99
學期2
發表日期2011/03/27
作品名稱Synthesis, characterization, and reactivity of dinitrosyl iron complexes stabilized by N-heterocyclic carbenes
作品名稱(其他語言)
著者Hess, Jennifer L.; Hsieh, Chung-Hung; Darensbourg, Marcetta Y.
作品所屬單位淡江大學化學學系
出版者
會議名稱241st ACS National Meeting & Exposition
會議地點Anaheim, CA, United States
摘要Dinitrosyl iron complexes (DNICs) with S, N, or O coordination function as nitric oxide transfer agents in biol. systems.1,2 However, the few model complexes contg. N-donor ligands, specifically modeling histidine coordination, are extremely air sensitive and difficult to isolate; studies of their reactivity are sparce.3 We report a series of complexes utilizing N-heterocyclic carbenes (NHCs) as mimics of imidazole and histidine ligands. The {Fe(NO)2}10 EPR-silent complexes Fe(NO)2(CO)(IMe), Fe(NO)2(CO)(Ii-Pr), Fe(NO)2
關鍵字
語言英文
收錄於
會議性質國際
校內研討會地點
研討會時間20110327~20110331
通訊作者
國別美國
公開徵稿Y
出版型式紙本
出處241st ACS National Meeting & Exposition, INOR-39
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