| 標題：Structural and spectroscopic features of mixed valent FeIIFeI complexes and factors related to the rotated configuration of diiron hydrogenase |
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| 學年 | 101 |
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| 學期 | 2 |
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| 發表日期 | 2013/04/07 |
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| 作品名稱 | Structural and spectroscopic features of mixed valent FeIIFeI complexes and factors related to the rotated configuration of diiron hydrogenase |
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| 作品名稱（其他語言） | |
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| 著者 | Hsieh, Chung-Hung; Erdem, Ozlen; Harman, Scott; Singleton, Michael; Reijerse, Edward; Lubitz, Wolfgang; Popescu, Codrina; Reibenspies, Jospeh; Brothers, Scott; Hall, Michael; et a |
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| 作品所屬單位 | 淡江大學化學學系 |
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| 出版者 | |
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| 會議名稱 | 245th ACS National Meeting & Exposition |
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| 會議地點 | New Orleans, LA, United States |
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| 摘要 | The compds. of this study served as structural and functional biomimetics of the [FeFe]-Hydrogenase active site and have demonstrated a redox level-dependent structural rearrangement that is unique in dinuclear organometallic chem. The distinctive "rotated", as contrasted to sym. butterfly, structure is the epicenter of the natural, base metal, hydrogen-producing catalysts. The installation of bridgehead bulk in the -SCH2CR2CH2S- dithiolate (R = Me, Et) model complexes produces 6-membered FeS2C3 cyclohexane-type rings that in the boat c... |
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| 關鍵字 | |
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| 語言 | 英文 |
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| 收錄於 | |
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| 會議性質 | 國際 |
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| 校內研討會地點 | |
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| 研討會時間 | 20130407~20130411 |
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| 通訊作者 | |
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| 國別 | 美國 |
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| 公開徵稿 | Y |
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| 出版型式 | 紙本 |
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| 出處 | 245th ACS National Meeting & Exposition, INOR-285 |
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| 相關連結 | |
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