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標題:Structural and spectroscopic features of mixed valent FeIIFeI complexes and factors related to the rotated configuration of diiron hydrogenase
學年101
學期2
發表日期2013/04/07
作品名稱Structural and spectroscopic features of mixed valent FeIIFeI complexes and factors related to the rotated configuration of diiron hydrogenase
作品名稱(其他語言)
著者Hsieh, Chung-Hung; Erdem, Ozlen; Harman, Scott; Singleton, Michael; Reijerse, Edward; Lubitz, Wolfgang; Popescu, Codrina; Reibenspies, Jospeh; Brothers, Scott; Hall, Michael; et a
作品所屬單位淡江大學化學學系
出版者
會議名稱245th ACS National Meeting & Exposition
會議地點New Orleans, LA, United States
摘要The compds. of this study served as structural and functional biomimetics of the [FeFe]-Hydrogenase active site and have demonstrated a redox level-dependent structural rearrangement that is unique in dinuclear organometallic chem. The distinctive "rotated", as contrasted to sym. butterfly, structure is the epicenter of the natural, base metal, hydrogen-producing catalysts. The installation of bridgehead bulk in the -SCH2CR2CH2S- dithiolate (R = Me, Et) model complexes produces 6-membered FeS2C3 cyclohexane-type rings that in the boat c...
關鍵字
語言英文
收錄於
會議性質國際
校內研討會地點
研討會時間20130407~20130411
通訊作者
國別美國
公開徵稿Y
出版型式紙本
出處245th ACS National Meeting & Exposition, INOR-285
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