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標題:N2S2-nickel and iron nitrosyls as metallo ligands in synthetic analogs of the [FeFe]-H2ase enzyme active site
學年101
學期2
發表日期2013/04/07
作品名稱N2S2-nickel and iron nitrosyls as metallo ligands in synthetic analogs of the [FeFe]-H2ase enzyme active site
作品名稱(其他語言)
著者Darensbourg, Marcetta Y.; Hsieh, Chung-Hung; Ghosh, Pokhraj
作品所屬單位淡江大學化學學系
出版者
會議名稱245th ACS National Meeting & Exposition
會議地點New Orleans, LA, United States
摘要The unique diiron catalytic unit that exists in the active site of the [FeFe]-H2ase has obvious design features that have been exploited in the development of hydrogen processing catalysts utilizing earth abundant metals, nickel and iron. In particular, the pendant base feature within the bridging dithiolate has been adapted within a nickel-diphosphinocyclohexane-like ring providing a remarkable catalyst for H2 prodn.(Helm, Dubois, et al., Science, 2011 , 863-866) We will describe modifications of the (μ-S(CH2)3S)[Fe(CO)3]2 p..
關鍵字
語言英文
收錄於
會議性質國際
校內研討會地點
研討會時間20130407~20130411
通訊作者
國別美國
公開徵稿Y
出版型式紙本
出處245th ACS National Meeting & Exposition, INOR-636
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