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標題:Ligand-assisted proton delivery in diiron complexes as electrocatalysts for H2 production: Ligand and complex synthesis
學年101
學期2
發表日期2013/04/07
作品名稱Ligand-assisted proton delivery in diiron complexes as electrocatalysts for H2 production: Ligand and complex synthesis
作品名稱(其他語言)
著者Zaibaq, Nicholas; Ghosh, Pokhraj; Hsieh, Chung-Hung; Darensbourg, Marcetta Y.
作品所屬單位淡江大學化學學系
出版者
會議名稱245th ACS National Meeting & Exposition
會議地點New Orleans, LA, United States
摘要The active site of the enzyme diiron hydrogenase is of particular interest to inorg. chemists for its ability to catalyze the redn. of protons to form hydrogen gas. This group is interested in synthesizing biomimetic, organometallic analogs of the enzyme active site which may serve as affordable and efficient electrocatalysts of hydrogen prodn. This project in particular focuses mainly on synthesizing novel ligands contg. a Me and an amino group (or a substituted amino group) on the bridgehead carbon of a propanedithiolate ligand. Ligands that have been synthesized include the dithiolates ...
關鍵字
語言英文
收錄於
會議性質國際
校內研討會地點
研討會時間20130407~20130411
通訊作者
國別美國
公開徵稿Y
出版型式紙本
出處245th ACS National Meeting & Exposition, CHED-732
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