教師資料查詢 | 類別: 會議論文 | 教師: 謝忠宏 HSIEH, CHUNG-HUNG (瀏覽個人網頁)

標題:Iron-nitrosyl paradigm for base metal proton reduction electrocatalysis
學年102
學期1
發表日期2013/11/16
作品名稱Iron-nitrosyl paradigm for base metal proton reduction electrocatalysis
作品名稱(其他語言)
著者Darensbourg, Marcetta Y.; Hsieh, Chung-hung; Erdem, Ozlen; Ding, Shengda; Crouthers, Danielle; Lubitz, Wolfgang; Popescu, Codrina; Reibenspies, Joseph; Hall, Michael B.
作品所屬單位淡江大學化學學系
出版者
會議名稱69th Southwest Regional Meeting of the American Chemical Society
會議地點Waco, TX, United States
摘要Base metal, mol. catalysts for the fundamental process of conversion of protons and electrons to dihydrogen remain a substantial synthetic goal related to a sustainable energy future. A novel approach has produced a diiron complex with bridging thiolates in the butterfly shape of the 2Fe2S core of the [FeFe]-hydrogenase active site, but with NO rather than CO or CN- ligands, that is demonstrated to maintain structural integrity in two redox levels. Various spectroscopies corroborate the roles of the iron centers in electrocatalytic proton redn. The binuclear [(NO)Fe(N2
關鍵字
語言英文
收錄於
會議性質國際
校內研討會地點
研討會時間20131116~20131119
通訊作者
國別美國
公開徵稿Y
出版型式紙本
出處69th Southwest Regional Meeting of the American Chemical Society, SWRM-576
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