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標題:Electronic effects of metallodithiolate ligands on [FeFe]-H2ase active site model compounds
學年101
學期2
發表日期2013/04/07
作品名稱Electronic effects of metallodithiolate ligands on [FeFe]-H2ase active site model compounds
作品名稱(其他語言)
著者Ghosh, Pokhraj; Hsieh, Chung-Hung; Darensbourg, Marcetta Y.
作品所屬單位淡江大學化學學系
出版者
會議名稱245th ACS National Meeting & Exposition
會議地點New Orleans, LA, United States
摘要The reversible redn. of protons to form hydrogen gas is known to be catalyzed by the active-site of the diiron hydrogenase, [FeFe]-H2ase. The N2S2Ni (square planar), N2S2-Co(NO) and -Fe(NO) (square pyramidal) compds. are particularly interesting as the cis-dithiolates are noted for their nucleophilicity toward a diverse variety of electrophiles and their ability to lower the redn. potentials on coordination with M(CO)x. In this project a series of [FeFe]-H2ase active site model compds. are shown to form stable addu...
關鍵字
語言英文
收錄於
會議性質國際
校內研討會地點
研討會時間20130407~20130411
通訊作者
國別美國
公開徵稿Y
出版型式紙本
出處245th ACS National Meeting & Exposition, INOR-281
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