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標題:Ambidentate thiocyanate ligand in dinitrosyl iron complexes
學年101
學期2
發表日期2013/04/07
作品名稱Ambidentate thiocyanate ligand in dinitrosyl iron complexes
作品名稱(其他語言)
著者Hsieh, Chung-Hung; Brothers, Scott M.; Hall, Michael B.; Popescu, Codrina V.; Darensbourg, Marcetta Y.
作品所屬單位淡江大學化學學系
出版者
會議名稱245th ACS National Meeting & Exposition
會議地點New Orleans, LA, United States
摘要Ambidentate ligands such as thiocyanate (SCN-), cyanate (OCN-) and azide (N3 -) have played important roles in the development of bonding models relating to factors that control linkage isomerism in transition metal complexes. However, examples of DNICs, for which oxidn. states of iron are ambiguous, contg. these ambidentate ligands are rare. Two redox levels are prevalent for DNICs, represented in the Enemark-Feltham (E-F) notation as {Fe(NO)2}9 and {Fe(NO)2}10 for oxidized and reduced levels resp., eac...
關鍵字
語言英文
收錄於
會議性質國際
校內研討會地點
研討會時間20130407~20130411
通訊作者
國別美國
公開徵稿Y
出版型式紙本
出處245th ACS National Meeting & Exposition, INOR-96
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