| 標題：cis-Dithiolatonickel as metalloligand to dinitrosyl iron units: the di-metallic structure of Ni(l-SR)[Fe(NO)2] and an unexpected, abbreviated metalloadamantyl cluster, Ni2(l-SR)4[Fe(NO)2]3 |
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| 學年 | 99 |
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| 學期 | 2 |
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| 出版（發表）日期 | 2011/05/01 |
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| 作品名稱 | cis-Dithiolatonickel as metalloligand to dinitrosyl iron units: the di-metallic structure of Ni(l-SR)[Fe(NO)2] and an unexpected, abbreviated metalloadamantyl cluster, Ni2(l-SR)4[Fe(NO)2]3 |
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| 作品名稱（其他語言） | |
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| 著者 | Hsieh, Chung-Hung; Chupik, Rachel B.; Brothers, Scott M.; Hall, Michael B.; Darensbourg, Marcetta Y. |
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| 單位 | 淡江大學化學學系 |
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| 出版者 | Cambridge: R S C Publications |
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| 著錄名稱、卷期、頁數 | Dalton Transactions 40(22), pp.6047-6053 |
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| 摘要 | The reaction of Fe(CO)2(NO)2 and Ni(N2S2) (N2S2 = N,N′-Bis(2-mercaptoethyl)-1,4-diazacycloheptane) by a single CO replacement yields [Ni(N2S2)]Fe(NO)2(CO), while an excess of Fe(CO)2(NO)2 leads to triply bridging thiolate sulphurs in a cluster of core composition Ni2S4Fe3, lacking one Fe(NO)2 unit to complete the adamantane-like structure. This structural type was earlier identified in a CuICl aggregate of MII(N2S2) (MII = Ni, Cu), in which complete MII2S4CuI4 core structures were obtained as the major, and, in the case of CuII(N2S2), the incomplete CuII2S4CuI3 as a minor, product. The full Ni2S4Fe4 cluster has not yet been realized for Fe = Fe(NO)2. Computational analysis of the NiFe-heterobimetallic complex addresses structural issues including a ∠Ni–S–Fe of 90° in the bimetallic complex. |
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| 關鍵字 | |
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| 語言 | 英文 |
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| ISSN | 1477-9226;1477-9234 |
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| 期刊性質 | 國外 |
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| 收錄於 | |
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| 產學合作 | |
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| 通訊作者 | Darensbourg, Marcetta Y. |
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| 審稿制度 | 是 |
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| 國別 | 英國 |
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| 公開徵稿 | |
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| 出版型式 | 紙本;電子版 |
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| 相關連結 | |
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