教師資料查詢 | 類別: 期刊論文 | 教師: 謝忠宏 HSIEH, CHUNG-HUNG (瀏覽個人網頁)

標題:A dinitrosyl iron complex as a platform for metal-bound imidazole to N-heterocyclic carbene conversion
學年102
學期1
出版(發表)日期2013/08/16
作品名稱A dinitrosyl iron complex as a platform for metal-bound imidazole to N-heterocyclic carbene conversion
作品名稱(其他語言)
著者Hsieh, Chung-Hung; Pulukkody, Randara; Darensbourg, Marcetta Y.
單位淡江大學化學學系
出版者Cambridge: R S C Publications
著錄名稱、卷期、頁數Chemical Communications 49(81), pp.9326-9328
摘要An N-alkyl imidazole bearing a neutral {Fe(NO)2}10 dinitrosyliron complex (DNIC) when treated with sodium t-butoxide undergoes base-promoted conversion to the N-heterocyclic carbene (NHC)–DNIC, while maintaining the Fe(NO)2 unit intact. Subsequent alkylation led to the isolation of the NHC–DNIC product; further nitrosylation led to trinitrosyl (NHC)Fe(NO)3+. Both were isolated and structurally characterized.
關鍵字
語言英文
ISSN1364-548X
期刊性質國外
收錄於SCI;
產學合作
通訊作者Darensbourg, Marcetta Y.
審稿制度
國別英國
公開徵稿
出版型式,電子版,紙本
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