教師資料查詢 | 類別: 期刊論文 | 教師: 林諭男 I-nan Lin (瀏覽個人網頁)

標題:Ultra-nanocrystalline diamond nanowires with enhanced electrochemical properties
學年101
學期2
出版(發表)日期2013/03/01
作品名稱Ultra-nanocrystalline diamond nanowires with enhanced electrochemical properties
作品名稱(其他語言)
著者Jayakumar Shalini; Lin, Yi-Chieh; Chang, Ting-Hsun; Kamatchi Jothiramalingam Sankaran; Chen, Huang-Chin; Lin, I-Nan; Lee, Chi-Young; Tai, Nyan-Hwa
單位淡江大學物理學系
出版者Kidlington: Pergamon
著錄名稱、卷期、頁數Electrochimica Acta 92, pp.9–19
摘要The effects of N2 incorporation in Ar/CH4 plasma on the electrochemical properties and microstructure of ultra-nanocrystalline diamond (UNCD) films are reported. While the electrical conductivity of the films increased monotonously with increasing N2 content (up to 25%) in the plasma, the electrochemical behavior was optimized for UNCD films grown in (Ar–10% N2)/CH4 plasma. Transmission electron microscopy showed that the main factor resulting in high conductivity in the films was the formation of needle-like nanodiamond grains and the induction graphite layer encapsulating these grains. The electrochemical process for N2-incorporated UNCD films can readily be activated due to the presence of nanographite along the grain boundaries of the films. The formation of needle-like diamond grains was presumably due to the presence of CN species that adhered to the existing nanodiamond clusters, which suppressed radial growth of the nanodiamond crystals, promoting anisotropic growth and the formation of needle-like nanodiamond. The N2-incorporated UNCD films outperformed other electrochemical electrode materials, such as boron-doped diamond and glassy carbon, in that the UNCD electrodes could sense dopamine, urea, and ascorbic acid simultaneously in the same mixture with clear resolution.
關鍵字N2-doped UNCD; Electrical conductivity; Nanographite; Electrochemical property
語言英文
ISSN0013-4686
期刊性質
收錄於
產學合作
通訊作者
審稿制度
國別英國
公開徵稿
出版型式紙本
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