| 標題：Synthesis, spectroscopic and magnetic properties of the charge-transfer complex Bifc.C60 |
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| 學年 | 85 |
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| 學期 | 2 |
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| 出版（發表）日期 | 1997/02/01 |
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| 作品名稱 | Synthesis, spectroscopic and magnetic properties of the charge-transfer complex Bifc.C60 |
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| 作品名稱（其他語言） | |
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| 著者 | Wang, Wen Jwu; Lay, Y. L.; Chang, Chen Shen; Chiu, Haw Shyi; Chuang, Kuo Shen; Wang, Bo Cheng |
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| 單位 | 淡江大學化學學系 |
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| 出版者 | Lausanne: Elsevier S.A. |
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| 著錄名稱、卷期、頁數 | Synthetic Metals 86(1 -3 pt 3), pp.2293-2294 |
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| 摘要 | Charge-transfer complex of C60 with 1,1'-biferrocene(Bifc) was prepared. The charge-transfer property was investigated by infrared and uv/vis/nir spectroscopy. The charge-transfer process was studied in detail by electron paramagnetic resonance spectroscopy. A complex reaction behavior has been observed. Studies of variable temperature EPR in the solid state show g-value shift as well as with peak-width change. A relaxation with degradation process of this charge-transfer complex was proposed. Magnetic studies conducted by SQUID magnetometer show that the magnetic behavior of these charge-transfer complexes could be described as superposition of paramagnetic and ferromagnetic components. The coercive forces and residual magnetizations of these complexes measured at low temperature are discussed. |
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| 關鍵字 | Charge transfer;Chemical reactions;Coercive force;Degradation;Electron spin resonance spectroscopy;Infrared spectroscopy;Magnetic properties;Magnetic variables measurement;Magnetization;Magnetometers;SQUIDs;Synthesis (chemical);Biferrocene;Charge transfer complex;Charge transfer property;G value shift;Peak width change;Ultraviolet visible near infrared spectroscopy;Organic conductors |
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| 語言 | 英文 |
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| ISSN | 0379-6779 |
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| 期刊性質 | 國外 |
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| 收錄於 | |
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| 產學合作 | |
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| 通訊作者 | |
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| 審稿制度 | |
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| 國別 | 史瓦濟蘭 |
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| 公開徵稿 | |
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| 出版型式 | 紙本 |
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| 相關連結 | |
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