教師資料查詢 | 類別: 期刊論文 | 教師: 王文竹 WANG, WEN-JWU (瀏覽個人網頁)

標題:New Copper(I) Complex with Triazole Derivative Ligand Containing α-Diimine Moiety: Synthesis, Structure, Luminescence and Electrochemistry
學年95
學期1
出版(發表)日期2006/12/01
作品名稱New Copper(I) Complex with Triazole Derivative Ligand Containing α-Diimine Moiety: Synthesis, Structure, Luminescence and Electrochemistry
作品名稱(其他語言)
著者王文竹; Wang, Wen-jwu; 林建合; Lin, Chien-ho
單位淡江大學化學學系
出版者臺北市中國化學學會
著錄名稱、卷期、頁數Journal of the Chinese Chemical Society=中國化學會會誌 53(6), pp.1309-1316
摘要One cuprous complex [Cu(L)(PPh3)I] was obtained by reaction of [Cu(PPh3)3I] (PPh3 = triphenylphosphine) with a new a-diimine ligand L (N-diphenylmethylene-3,5-di(2'-pyridyl)-4-amino-1,2,4-triazole). The complex has been characterized by UV-Vis, luminescence, 1H NMR spectroscopy and cyclic voltammetric study. The structure of ligand L and complex are confirmed by single crystal X-ray diffraction study. The compound [Cu(L)(PPh3)I] crystallizes in the monoclinic P21/c space group with a = 19.9291(4), b = 10.0691(2), c = 21.9245(5), α = γ = 90, β = 92.481(10), and Z = 4. The complex shows a MLCT band in the 350~545 nm region and exhibits luminescent emission at 600 nm at room temperature in dichloromethane solution. Cyclic voltammogram of [Cu(L)(PPh3)I] shows a quasi-reversible redox couple of the copper center at 0.67 V for Cu(I)/Cu(II) and an irreversible reduction potential at -0.98 V accompanied by a stripping peak of copper at -0.11 V for Cu(I)/Cu(0).
關鍵字
語言英文
ISSN0009-4536
期刊性質國內
收錄於SCI;
產學合作
通訊作者
審稿制度
國別中華民國
公開徵稿
出版型式,紙本
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