Magnetic Properties of M3[Fe(CN)6]2•XH2O (M=Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ), Zn(Ⅱ)) | |
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學年 | 84 |
學期 | 1 |
出版(發表)日期 | 1995-10-01 |
作品名稱 | Magnetic Properties of M3[Fe(CN)6]2•XH2O (M=Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ), Zn(Ⅱ)) |
作品名稱(其他語言) | |
著者 | 徐惠麗; Shyu, H. L.; 林施娜; Lin, S. N.; 魏和祥; Wei, Ho-hsiang |
單位 | 淡江大學化學學系 |
出版者 | 臺北市:中國化學學會 |
著錄名稱、卷期、頁數 | Journal of the Chinese Chemical Society=中國化學會會誌 42(5), pp.791-795 |
摘要 | Compounds of the type M/sub 3/ [ Fe(CN)/sub 6/ ]/sub 2/-XH/sub 2/O (M=Co(II), Ni(II), Cu(II), and Zn(II)) were prepared and magnetic properties of their powders were investigated by means of EPR spectra, Mossbauer effect and magnetic susceptibility measurements. The temperature dependence of the magnetization for the complexes Co/sub 3/ [ Fe(CN)/sub 6/ ] /sub 2/-10H/sub 2/O, Ni/sub 3/ [ Fe(CN)/sub 6/ ] /sub 2/-10H/sub 2/O and Cu/sub 3/ [ Fe(CN)/sub 6/] /sub 2/-4H/sub 2/O revealed that below the critical temperatures 15, 22 and 20K respectively, these complexes have zero-field magnetization. The magnetic hysteresis at 10K for Co(II), Ni(II) and Cu(II) complexes was observed. Mossbauer spectra at 4.2K for the compounds are discussed. |
關鍵字 | Molecular Magnet;Mossbauer Effect;Cyanoferrate;Temperature Dependence;Magnetic Hysteresis;分子磁鐵;Mossbauer效應;氰高鐵酸鹽;溫度依從;磁滯 |
語言 | en |
ISSN | 0009-4536 |
期刊性質 | 國內 |
收錄於 | SCI |
產學合作 | |
通訊作者 | |
審稿制度 | |
國別 | TWN |
公開徵稿 | |
出版型式 | 紙本 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25035 ) |