Correlation Between Polarographic Half-Wave Potentials and Electronic Spectra of Cis-Trans Complexes of Chromium (Ⅲ) and Rhodium (Ⅲ)
學年 66
學期 1
出版（發表）日期 1977-12-01
作品名稱 Correlation Between Polarographic Half-Wave Potentials and Electronic Spectra of Cis-Trans Complexes of Chromium (Ⅲ) and Rhodium (Ⅲ)
作品名稱（其他語言）
著者 Wei, Ho-hsiang
單位 淡江大學化學學系
出版者 臺北市：中國化學學會
著錄名稱、卷期、頁數 Journal of the Chinese Chemical Society 24(4)，頁147-156
摘要 A linear correlation between half-wave potential (E1/2) for the process M(III)→M(II) and the first d-d transition band (v) of the types cis and trans-[M(en)2X2]n+ (M=Cr(III), and Rh(III), X=ONO¯, NCS¯, F¯, Cl¯, Br¯, I¯, H2O, DMF, DMSO, n=1, 3) was found. The plots of the difference in half-wave potential (⊿E1/2) against the difference in the first d-d transition band (⊿v) for the cis and trans isomer are straight lines. The equations, E1/2=β/nαF+K1 and ⊿E1/2=(β/NαF)⊿ε were derived, and used to describe the linear correlations between polarographic behavior and electronic spectrum.
關鍵字
語言 en
ISSN 0009-4536
期刊性質 國內
收錄於 SCI
產學合作
通訊作者
審稿制度 否
國別 TWN
公開徵稿
出版型式 ,紙本
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