教師資料查詢 | 類別: 期刊論文 | 教師: 魏和祥 WEI, HO-HSIANG (瀏覽個人網頁)

標題:Correlation Between Polarographic Half-Wave Potentials and Electronic Spectra of Cis-Trans Complexes of Chromium (Ⅲ) and Rhodium (Ⅲ)
學年66
學期1
出版(發表)日期1977/12/01
作品名稱Correlation Between Polarographic Half-Wave Potentials and Electronic Spectra of Cis-Trans Complexes of Chromium (Ⅲ) and Rhodium (Ⅲ)
作品名稱(其他語言)
著者魏和祥; Wei, Ho-hsiang; Li, Ting-tung
單位淡江大學化學學系
出版者臺北市中國化學學會
著錄名稱、卷期、頁數中國化學會會誌=Journal of the Chinese Chemical Society 24(4)頁147-156
摘要A linear correlation between half-wave potential (E1/2) for the process M(III)→M(II) and the first d-d transition band (v) of the types cis and trans-[M(en)2X2]n+ (M=Cr(III), and Rh(III), X=ONO¯, NCS¯, F¯, Cl¯, Br¯, I¯, H2O, DMF, DMSO, n=1, 3) was found. The plots of the difference in half-wave potential (⊿E1/2) against the difference in the first d-d transition band (⊿v) for the cis and trans isomer are straight lines. The equations, E1/2=β/nαF+K1 and ⊿E1/2=(β/NαF)⊿ε were derived, and used to describe the linear correlations between polarographic behavior and electronic spectrum.
關鍵字
語言英文
ISSN0009-4536
期刊性質國內
收錄於SCI
產學合作
通訊作者
審稿制度
國別中華民國
公開徵稿
出版型式紙本
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