教師資料查詢 | 類別: 期刊論文 | 教師: 魏和祥 WEI, HO-HSIANG (瀏覽個人網頁)

標題:Magnetic Hyperfine Mössbauer Spectra of Ferrocenyaldimines-FeCl3 Adducts
學年82
學期1
出版(發表)日期1993/08/01
作品名稱Magnetic Hyperfine Mössbauer Spectra of Ferrocenyaldimines-FeCl3 Adducts
作品名稱(其他語言)
著者李綺縑; Lee, C. J.; 魏和祥; Wei, Ho-hsiang
單位淡江大學化學學系
出版者臺北市中國化學學會
著錄名稱、卷期、頁數Journal of the Chinese Chemical Society=中國化學會會誌 40(4), pp.355-359
摘要Ferrocenylaldimines (Fc-CH=N-R) were prepared by condensation of Schiff base of formylferrocene with polyacenylamines RNH/sub 2/; R=naphthyl, anthracenyl and pyrenyl groups. This step was followed by oxidation with FeCl/sub 3/ to give [ Fc-CH=NR ] - FeCl/sub 3/ adducts. The electronic state of iron in these adducts was investigated by means of /sup 57/Fe Mossbauer spectra except for [ Fc-CH=N-Pyr ] -FeCl/sub 3/ showed that only a doublet was observed at ambient temperature. As the temperature was decreased below 200K, additional magnetic hyperfine splitting was observed characteristic of ferric oxide.
關鍵字
語言英文
ISSN0009-4536
期刊性質國內
收錄於SCI;
產學合作
通訊作者
審稿制度
國別中華民國
公開徵稿
出版型式,紙本
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