| Synthesis and Mossbauer Spectra Studies of Mono-Binuclear Iron (III) Complexes with a Quinquedentate Ligand Derived from Salicylaldehyeds and Diethylenetriamine | |
|---|---|
| 學年 | 78 |
| 學期 | 1 |
| 出版（發表）日期 | 1989-12-01 |
| 作品名稱 | Synthesis and Mossbauer Spectra Studies of Mono-Binuclear Iron (III) Complexes with a Quinquedentate Ligand Derived from Salicylaldehyeds and Diethylenetriamine |
| 作品名稱（其他語言） | |
| 著者 | 許進福; Sheu, Jinn-fu; 魏和祥; Wei, Ho-hsiang |
| 單位 | 淡江大學化學學系 |
| 出版者 | 臺北市：中國化學學會 |
| 著錄名稱、卷期、頁數 | Journal of the Chinese Chemical Society=中國化學會會誌 36(6), pp.539-543 |
| 摘要 | Mono- and binuclear iron(III) complexes of general formula (FeXL) and (LFe-Y-FeL)(Bph/sub 4/)/sub 2/ have been prepared, and their spin state of iron atom in the complexes has been studied by means of the temperature dependence of the Mossbauer spectra, electronic spectra and magnetic measurement, where X is a monodentate ligand such as Cl/sup -/, NCS/sup -/, NCO/sup -/, N/sub 3//sup -/, pyridine and L denotes a quinquedentate Schiff base derived from salicylaldehyde and diethylenetriamine, and Y denotes a bridged ligand such as pyrazine (pyr), 4,4'-bipyridine(bpy) and 4,4'-vinylenebipyridine (vibpy). On the basis of the Mossbauer and magnetic data, it was concluded that these complexes were all the high-spin (S=5/2) state. The effect of gamma-ray irradiation for these complexes has been discussed. |
| 關鍵字 | Mossbauer Effect;Binuclear Iron(Iii) Complex;Gamma-Ray Irradiation;Iron Complexes;穆斯鮑爾效應;雙核三價鐵離子錯化物;鐵錯化物;.gamma.射線放射 |
| 語言 | en |
| ISSN | 0009-4536 |
| 期刊性質 | 國內 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | 紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25293 ) |
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