教師資料查詢 | 類別: 期刊論文 | 教師: 魏和祥 WEI, HO-HSIANG (瀏覽個人網頁)

標題:Synthesis and Mossbauer Spectra Studies of Mono-Binuclear Iron (III) Complexes with a Quinquedentate Ligand Derived from Salicylaldehyeds and Diethylenetriamine
學年78
學期1
出版(發表)日期1989/12/01
作品名稱Synthesis and Mossbauer Spectra Studies of Mono-Binuclear Iron (III) Complexes with a Quinquedentate Ligand Derived from Salicylaldehyeds and Diethylenetriamine
作品名稱(其他語言)
著者許進福; Sheu, Jinn-fu; 魏和祥; Wei, Ho-hsiang
單位淡江大學化學學系
出版者臺北市中國化學學會
著錄名稱、卷期、頁數Journal of the Chinese Chemical Society=中國化學會會誌 36(6), pp.539-543
摘要Mono- and binuclear iron(III) complexes of general formula (FeXL) and (LFe-Y-FeL)(Bph/sub 4/)/sub 2/ have been prepared, and their spin state of iron atom in the complexes has been studied by means of the temperature dependence of the Mossbauer spectra, electronic spectra and magnetic measurement, where X is a monodentate ligand such as Cl/sup -/, NCS/sup -/, NCO/sup -/, N/sub 3//sup -/, pyridine and L denotes a quinquedentate Schiff base derived from salicylaldehyde and diethylenetriamine, and Y denotes a bridged ligand such as pyrazine (pyr), 4,4'-bipyridine(bpy) and 4,4'-vinylenebipyridine (vibpy). On the basis of the Mossbauer and magnetic data, it was concluded that these complexes were all the high-spin (S=5/2) state. The effect of gamma-ray irradiation for these complexes has been discussed.
關鍵字Mossbauer Effect;Binuclear Iron(Iii) Complex;Gamma-Ray Irradiation;Iron Complexes;穆斯鮑爾效應;雙核三價鐵離子錯化物;鐵錯化物;.gamma.射線放射
語言英文
ISSN0009-4536
期刊性質國內
收錄於SCI
產學合作
通訊作者
審稿制度
國別中華民國
公開徵稿
出版型式紙本
相關連結
Google+ 推薦功能,讓全世界都能看到您的推薦!