| Proton magnetic resonance studies of heterocyclic aromatic amine adducts of nickel(II) and cobalt(II) acetylacetonate | |
|---|---|
| 學年 | 67 |
| 學期 | 1 |
| 出版（發表）日期 | 1978-12-01 |
| 作品名稱 | Proton magnetic resonance studies of heterocyclic aromatic amine adducts of nickel(II) and cobalt(II) acetylacetonate |
| 作品名稱（其他語言） | |
| 著者 | 王文竹; Wang, Wen-jwu; Wei, Ho-hsiang; 魏和祥 |
| 單位 | 淡江大學化學學系 |
| 出版者 | 臺北市：中國化學學會 |
| 著錄名稱、卷期、頁數 | 中國化學會會誌=Journal of the Chinese Chemical Society 25(4)，頁185-194 |
| 摘要 | The proton nmr isotropic shifts of pyridine type ligands coordinated to paramagnetic nickel(II) and cobalt(II) acetylacetonate are reported, and the mechanisms of unpaired electron spin delocalization in these complexes are discussed. It is found that a σ-delocalization mechanism is in dominant, but the π-contribution can not be rule out. The calculations of the geometric factor for Co(II) complexes are done. It is used in the ratio method to separate the contribution of pseudo-contact shift from isotropic shift for Co(II) complexes. The effect of pseudoaromatic chelate ring on contact shift is not so large as previous reported. |
| 關鍵字 | |
| 語言 | en |
| ISSN | 0009-4536 |
| 期刊性質 | 國內 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | 王文竹; Wang, Wen-jwu; Wei, Ho-hsiang; 魏和祥 |
| 審稿制度 | 否 |
| 國別 | TWN |
| 公開徵稿 | |
| 出版型式 | ,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/61696 ) |
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