Monte Carlo simulation of diepoxides and monoepoxides cured with amines
學年 91
學期 1
出版（發表）日期 2002-09-01
作品名稱 Monte Carlo simulation of diepoxides and monoepoxides cured with amines
作品名稱（其他語言）
著者 Cheng, kuo-chung; Don, trong-ming; Rwei, syang-peng; Li, yu-ching; Duann, yen-fang
單位 淡江大學化學工程與材料工程學系
出版者 Hoboken: John Wiley & Sons, Inc.
著錄名稱、卷期、頁數 Journal of Polymer Science, Part B: Polymer Physics 40(17), pp.1857-1868
摘要 The diepoxide–monoepoxide–diamine curing systems are investigated with a Monte Carlo simulation. The dependence of the molecular weight distribution (MWD), gel fraction, and cycle rank of the polymers on the differences in the epoxy reactivities and the contents of the monoepoxide as a reactive diluent are discussed. Before gelation, the MWD of the curing systems with a lower content of the monoepoxide is broader than the MWD of the curing systems with a higher content, and it leads to a lower critical conversion. The gel fraction and cycle rank of the polymers decrease with an increasing amount of the diluent. Even fully cured, the system with a 0.6 epoxy molar fraction of the monoepoxide still has a large fraction of sol, about 49%. Although the various reactivities of the monoepoxide result in different ways of forming gels during curing, the final gel fractions are always near 100% as long as the epoxy molar fraction of the diluent is no more than 0.2. The profiles of the molecular weights of the polymers calculated by the model are in agreement with the experimental data. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 1857–1868, 2002
關鍵字 Amines;Computer simulation;Curing;Gelation;Gels;Molecular weight;Molecular weight distribution;Monte Carlo methods;Reaction kinetics;Sols;Cycle rank;Diamine;Diepoxides;Gel fraction;Molar mass distribution;Monoepoxides;Epoxy resins
語言 en
ISSN 0887-6266
期刊性質 國外
收錄於 SCI EI
產學合作
通訊作者 Cheng, kuo-chung
審稿制度
國別 USA
公開徵稿
出版型式 紙本
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