| 標題：A new tri-functional azetidine compound for self-curing aqueous-based PU system |
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| 學年 | 100 |
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| 學期 | 2 |
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| 出版（發表）日期 | 2012/04/01 |
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| 作品名稱 | A new tri-functional azetidine compound for self-curing aqueous-based PU system |
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| 作品名稱（其他語言） | |
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| 著者 | Wang, Shih-Chieh; Chen, Po-Chen; Hwang, Jing-Zhong; Huang, Chi-Yuan; Yeh, Jen-Taut; Chen, Kan-Nan |
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| 單位 | 淡江大學化學學系;淡江大學化學工程與材料工程學系 |
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| 出版者 | Hoboken: John Wiley & Sons, Inc. |
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| 著錄名稱、卷期、頁數 | Journal of Applied Polymer Science 124(1), pp.175–181 |
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| 摘要 | A mono-azetidine compound had been demonstrating a ring opening reaction with carboxylic acid (e.g., trimethylacetic acid, TMAA) and that resulted in an amino ester bond formation at ambient temperature. A triazetidine compound (trimethylolpropane tris(1-azetidinyl)propionate, TMPTA-AZT) was obtained via Michael addition of azetidine (AZT) to trimethylolpropane triacrylate (TMPTA). The carboxylic groups of anionic aqueous-based polyurethanes (PU) served as internal emulsifier, which stabilized PU dispersion and also served as PU curing sites. The triazetidine compound (TMPTA-AZT) was introduced into anionic aqueous-based PU dispersion as a new latent curing agent and that mixture became a single-component self-curable aqueous PU system. A crosslinked PU film was obtained from this PU system on drying at ambient temperature. The final polymer performance properties demonstrated the crosslinking behaviors of this new curing agent, TMPTA-AZT, with carboxylic ion-containing aqueous-based PU resins. |
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| 關鍵字 | self-curing; azetidine; ring-opening; aqueous-based PU; Michael addition |
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| 語言 | 英文 |
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| ISSN | 1097-4628 |
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| 期刊性質 | 國外 |
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| 收錄於 | SCI |
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| 產學合作 | |
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| 通訊作者 | 陳幹男 (knchen@mail.tku.edu.tw) |
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| 審稿制度 | 是 |
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| 國別 | 美國 |
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| 公開徵稿 | |
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| 出版型式 | 電子版 |
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| 相關連結 | |
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