Correlation between polarographic halfwave potential and electronic spectra of cis-trans compleses of chromium(III) and rhodium(III)
學年 66
學期 1
出版（發表）日期 1977-12-01
作品名稱 Correlation between polarographic halfwave potential and electronic spectra of cis-trans compleses of chromium(III) and rhodium(III)
作品名稱（其他語言）
著者 Wei, Ho-hsiang
單位 淡江大學化學學系
出版者
著錄名稱、卷期、頁數 Journal of the Chinese chemical society24(4),　p.147-156
摘要 A linear correlation between half-wave potential (E1/2) for the process M(III)→M(II) and the first d-d transition band (v) of the types cis and trans-[M(en)2X2]n+ (M=Cr(III) and Rh(III), X=ONO−, NCS−, F−, Cl−, Br−, I−, H2O, DMF, DMSO, n=1, 3) was found. The plots of the difference in half-wave potential (ΔE1/2) against the difference in the first d-d transition hand (Δv) for the cis and trans isomer are straight lines. The equations, E1/2=β/nαF+K1 and ΔE1/2=(β/NαF)Δ were derived, and used to describe the linear correlations between polarographic behavior and electronic spectrum.
關鍵字
語言 en
ISSN 2192-6549
期刊性質 國內
收錄於
產學合作
通訊作者
審稿制度 否
國別 TWN
公開徵稿
出版型式 ,電子版
相關連結

機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/61546 )

機構典藏連結