教師資料查詢 | 類別: 期刊論文 | 教師: 陳幹男CHEN KAN-NAN (瀏覽個人網頁)

標題:Organonitrogen derivatives of metal carbonyls. 10. Cyclopentadienylmetal dicarbonyl ketoximato derivatives of molybdenum and tungsten
學年65
學期2
出版(發表)日期1977/05/01
作品名稱Organonitrogen derivatives of metal carbonyls. 10. Cyclopentadienylmetal dicarbonyl ketoximato derivatives of molybdenum and tungsten
作品名稱(其他語言)
著者Chen, Kan-nan; King, R. B.
單位淡江大學化學學系
出版者American Chemical Society
著錄名稱、卷期、頁數Inorganic chemistry 16(5), pp.1164-1167
摘要Compounds of the type RR’CNOM(C0)2CSHS (M = Mo and W; R’ = CH3, R = CH3, CH=CH2, CH=C(CH3)2, and
(CHJ2CH=CH2; R + R’ = (CH,),) can be prepared by the following three methods: (1) reaction of RR’C=NOSn(CH3)’ with CSH5M(CO),CL; (2) reaction of RR’C==NOLi with CSH5M(CO),C1; (3) reaction of RR’C=NOH with CSH5M(C0)3CI in the presence of pyridine. Ultraviolet irradiation is necessary for the syntheses of the tungsten compounds but not for their molybdenum analogues. The proton and carbon-1 3 NMR spectra of the ten RR’CNOM(C0)2C5H5 derivatives are described and discussed.
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語言英文
ISSN0020-1669;1520-510X
期刊性質國外
收錄於SCI
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