教師資料查詢 | 類別: 期刊論文 | 教師: 董崇民 Don, Trong-ming (瀏覽個人網頁)

標題:Kinetic behavior of photo-polymerization of UV-curable resins with carboxylic acid and amino groups
學年98
學期2
出版(發表)日期2010/02/15
作品名稱Kinetic behavior of photo-polymerization of UV-curable resins with carboxylic acid and amino groups
作品名稱(其他語言)
著者Kuo, Kuo-Huai; Chiu, Wen-Yen; Don, Trong-Ming
單位淡江大學化學工程與材料工程學系
出版者Hoboken: John Wiley & Sons, Inc.
著錄名稱、卷期、頁數Journal of Applied Polymer Science 115(4), pp.1982-1994
摘要Photo-polymerization behaviors of bisphenol-A epoxy diacrylate (EPA) and six kinds of EPA-derived resins containing different amounts of carboxylic acid, urethane, amide, and imide groups were studied by a photo differential scanning calorimetry. The dark polymerization was performed and pseudo-steady state assumption of growing radicals was made to obtain the kinetic constants for propagation, bimolecular termination, monomolecular termination, and the concentration of growing radicals of different resins as a function of extent of reaction. Compared with EPA, it was found that the rate of polymerization and kinetic constants of the six resins were relatively small because the mobility of reacting species in resins was restricted by carboxylic acid, urethane, amide, and imide groups. Finally, three different photo-initiators were used to initiate the polymerization, and their kinetic behaviors were compared. The effect of tertiary amine group of photo-initiator on the rate of polymerization of resins having carboxylic acid group and the initiator efficiency were discussed.
關鍵字kinetic behavior; photo-polymerization; UV-curable resins
語言英文
ISSN0021-8995; 1097-4628
期刊性質國外
收錄於SCI;EI
產學合作
通訊作者Chiu, Wen-Yen
審稿制度
國別美國
公開徵稿
出版型式電子版
相關連結
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