教師資料查詢 | 類別: 期刊論文 | 教師: 董崇民 Don, Trong-ming (瀏覽個人網頁)

標題:Structures and properties of polycarbonate-modified epoxies from two different blending processes
學年88
學期1
出版(發表)日期1999/12/01
作品名稱Structures and properties of polycarbonate-modified epoxies from two different blending processes
作品名稱(其他語言)
著者Don, Trong-ming; Yeh, Chao-hsien; Bell, J. P.
單位淡江大學化學工程與材料工程學系
出版者Hoboken, NJ: John Wiley & Sons
著錄名稱、卷期、頁數Journal of applied polymer science 74(10), pp.2510-2521
摘要It has been proved in our previous study that during the melt-blending of an epoxy oligomer based on the diglycidyl ether of bisphenol-A (DGEBA) with polycarbonate (PC) at 200°C, the secondary hydroxyl groups in the DGEBA react with the carbonate groups in PC through transesterification, resulting in degraded PC chains with phenolic end groups and also in PC/DGEBA copolymers. Yet, in the same study, it was found that the prereactions between DGEBA and PC can be minimized or eliminated if a solution-blending process was used. Therefore, it was expected that, after being cured with a curing agent, different epoxy-network structures should result as a consequence of the two different premixing processes of DGEBA and PC. In addition, we also expect that in the melt-blending process, the fracture toughness of epoxies should be increased due to the incorporation of ductile PC chains into the epoxy network. In this study, therefore, we attempted to examine and compare the structures and properties of PC-modified epoxies through these two different blending processes.
關鍵字polycarbonate; epoxy; solution-blending process; melt-blending process; fracture toughness
語言英文
ISSN1097-4628;0021-8995;1097-4628
期刊性質國外
收錄於SCI;EI
產學合作
通訊作者
審稿制度
國別美國
公開徵稿
出版型式紙本
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