標題:Magnetic structure of α-FeC2O4‧2D2O |
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學年 | 75 |
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學期 | 2 |
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出版(發表)日期 | 1987/04/15 |
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作品名稱 | Magnetic structure of α-FeC2O4‧2D2O |
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作品名稱(其他語言) | |
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著者 | Satoru, Simizu; 陳憬燕; Chen, Jiing-yann; Friedberg, S. A.; Martinez, J.; Shirane, G. |
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單位 | 淡江大學物理學系 |
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出版者 | American Institute of Physics (AIP) |
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著錄名稱、卷期、頁數 | Journal of Applied Physics 61(8), pp.3420-3422 |
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摘要 | Long‐range spin ordering has been studied in the quasi‐one‐dimensional antiferromagnet α‐FeC2O4⋅2D2O by neutron diffraction on a powdered sample above and below T N =11.7 K. Data at 14 K show essentially the room‐temperature chemical structure. The space group is C2/c, Z=4, and unit cell dimensions are a=11.700 Å, b=5.568 Å, and c=9.847 Å with β=128.05°. Magnetic peaks appear at T N and data at 10.5 K show doubling of the unit cell along the b direction, the chain axis. The ordered structure belongs to the magnetic space group P 2b 2/n with spins parallel to the b axis. Cancellation of certain interchain interactions gives the structure a pronounced two‐dimensional character. At T 2=9.5 K a discontinuous transition to a second magnetic phase occurs with additional doubling of the unit cell in the a direction. Below T 2 the symmetry of the magnetic structure is reduced to triclinic, P 2s 1̄ with the spins deviating slightly from the b axis. |
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關鍵字 | |
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語言 | 英文 |
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ISSN | 0021-8979 |
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期刊性質 | 國內 |
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產學合作 | |
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通訊作者 | |
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審稿制度 | 否 |
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國別 | 美國 |
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公開徵稿 | |
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出版型式 | ,紙本 |
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