Electrophoresis of an Ellipsoid along the Axis of a Cylindrical Pore:  Effect of a Charged Boundary
學年 96
學期 2
出版(發表)日期 2008-03-01
作品名稱 Electrophoresis of an Ellipsoid along the Axis of a Cylindrical Pore:  Effect of a Charged Boundary
作品名稱(其他語言)
著者 曾琇瑱; Tseng, Shiojenn; Cho, Chia-hua; Chen, Zheng-syun; Hsu, Jyh-ping
單位 淡江大學數學學系
出版者 American Chemical Society (ACS)
著錄名稱、卷期、頁數 Langmuir 24(6), pp.2929-2937
摘要 The influence of a charged boundary on the electrophoretic behavior of a particle is investigated by considering the electrophoresis of a nonconducting ellipsoid along the axis of a cylindrical pore at the level of the linear Poisson−Boltzmann equation ignoring the polarization effect. The problem considered simulates the electrophoresis conducted in a narrow space such as capillary electrophoresis and electrophoresis through a porous medium. Here, because the effect of electroosmotic flow can be important the electrophoretic behavior is much more complicated than that for the case where a boundary is uncharged. The influences of the thickness of double layer, the aspect ratio of an ellipsoid, the relative radius of a pore, and the charge conditions on the ellipsoid and pore surfaces on the mobility of the ellipsoid are discussed. Several interesting but nonintuitive electrophoretic behaviors are observed.
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語言 en
ISSN 0743-7463
期刊性質 國內
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