Electrophoresis of an Ellipsoid along the Axis of a Cylindrical Pore: Effect of a Charged Boundary | |
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學年 | 96 |
學期 | 2 |
出版(發表)日期 | 2008-03-01 |
作品名稱 | Electrophoresis of an Ellipsoid along the Axis of a Cylindrical Pore: Effect of a Charged Boundary |
作品名稱(其他語言) | |
著者 | 曾琇瑱; Tseng, Shiojenn; Cho, Chia-hua; Chen, Zheng-syun; Hsu, Jyh-ping |
單位 | 淡江大學數學學系 |
出版者 | American Chemical Society (ACS) |
著錄名稱、卷期、頁數 | Langmuir 24(6), pp.2929-2937 |
摘要 | The influence of a charged boundary on the electrophoretic behavior of a particle is investigated by considering the electrophoresis of a nonconducting ellipsoid along the axis of a cylindrical pore at the level of the linear Poisson−Boltzmann equation ignoring the polarization effect. The problem considered simulates the electrophoresis conducted in a narrow space such as capillary electrophoresis and electrophoresis through a porous medium. Here, because the effect of electroosmotic flow can be important the electrophoretic behavior is much more complicated than that for the case where a boundary is uncharged. The influences of the thickness of double layer, the aspect ratio of an ellipsoid, the relative radius of a pore, and the charge conditions on the ellipsoid and pore surfaces on the mobility of the ellipsoid are discussed. Several interesting but nonintuitive electrophoretic behaviors are observed. |
關鍵字 | |
語言 | en |
ISSN | 0743-7463 |
期刊性質 | 國內 |
收錄於 | |
產學合作 | |
通訊作者 | |
審稿制度 | 否 |
國別 | TWN |
公開徵稿 | |
出版型式 | ,電子版 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/50389 ) |