A novel hexanuclear iron(III) complex containing three-coordination symmetries with two bridging μ-alkoxo groups, two μ3-oxo and four μ-catecholato bridges | |
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學年 | 96 |
學期 | 2 |
出版(發表)日期 | 2008-04-01 |
作品名稱 | A novel hexanuclear iron(III) complex containing three-coordination symmetries with two bridging μ-alkoxo groups, two μ3-oxo and four μ-catecholato bridges |
作品名稱(其他語言) | |
著者 | 魏和祥; Wei, Ho-hsiang; Lu, Jian-wei; Lin, Yi-wen; Takahahsi, Masashi |
單位 | 淡江大學化學學系 |
出版者 | Elsevier |
著錄名稱、卷期、頁數 | Inorganic Chemistry Communications 11(4), pp.388-391 |
摘要 | The reaction of stoichiometric amount of FeCl3, Schiff-base ligand, NaBPh4 in CH3CN and 3,5-DTBC in CH3OH under O2 did produce a new μ-oxo-bridged hexanuclear iron(III) cluster [Fe6(L)2(μ3-O)2(μ-3,5-DTBC)4(μ-CH3O)2(Cl)2] (BPh4)2 · 2H2O (1) (L = N,N-diethylenetriamino-bis(imidazolaldiminato) with a spin ground state of S = 5. |
關鍵字 | Iron(III) clusters;μ-Alkoxo–μ3-oxo–μ-catecholato bridges;Crystal structure;Magnetic properties;Mössbauer spectrum |
語言 | en |
ISSN | 1387-7003 |
期刊性質 | 國外 |
收錄於 | |
產學合作 | |
通訊作者 | |
審稿制度 | 否 |
國別 | NLD |
公開徵稿 | |
出版型式 | ,紙本 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25256 ) |