| A novel chloro-bridged tetranuclear cadmium(II) cluster with pyridyl-substituted nitronyl nitroxide: structure and magnetic properties | |
|---|---|
| 學年 | 89 |
| 學期 | 1 |
| 出版（發表）日期 | 2000-12-01 |
| 作品名稱 | A novel chloro-bridged tetranuclear cadmium(II) cluster with pyridyl-substituted nitronyl nitroxide: structure and magnetic properties |
| 作品名稱（其他語言） | |
| 著者 | 魏和祥; Wei, Ho-hsiang; Lee, Chin-Jhan; Lee, Gene-Hsiang; Wang, Yu |
| 單位 | 淡江大學化學學系 |
| 出版者 | Elsevier |
| 著錄名稱、卷期、頁數 | Inorganic Chemistry Communications 3(12), pp.690-693 |
| 摘要 | A tetranuclear cadmium(II) complex of 2(2-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1 H-imidazol-1-oxy 3-N-oxide (NIToPy) with CdCl2,[Cd4Cl8(NIToPy)4], has been structurally and magnetically characterized. The structure is based on a novel chloro-bridged tetranuclear cadmium quasi-cubane cluster, in which each cadmium atom is chelated by one NIToPy radical, and coordinated with four bridging chlorine atoms. The temperature dependence of the magnetic susceptibility measurements shows a weak ferromagnetic coupling between the radicals. An excellent simulation of the experimental data with the prism type four spins Hamiltonian H=−2J1(S1S2+S2S3+S3S4+S1S4)−2J2S2S4 obtained the parameters: Full-size image (<1 K), and g=2.04. |
| 關鍵字 | Cadmium compound;Nitronyl nitroxide;Crystal structure;Magnetic properties |
| 語言 | en |
| ISSN | 1387-7003 |
| 期刊性質 | 國外 |
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | NLD |
| 公開徵稿 | |
| 出版型式 | ,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25245 ) |
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