Ferromagnetic exchange in μ-alkoxo-μ-dicarboxylato double bridged tetranuclear copper(II) complexes: [Cu4(L-X)2(μ-C4H4O4)(dmf)2] (L = 1,3-bis(5-X-salicylideneamino)-2-propanol, X = Br, Cl) | |
---|---|
學年 | 93 |
學期 | 2 |
出版(發表)日期 | 2005-03-01 |
作品名稱 | Ferromagnetic exchange in μ-alkoxo-μ-dicarboxylato double bridged tetranuclear copper(II) complexes: [Cu4(L-X)2(μ-C4H4O4)(dmf)2] (L = 1,3-bis(5-X-salicylideneamino)-2-propanol, X = Br, Cl) |
作品名稱(其他語言) | |
著者 | 魏和祥; Wei, Ho-hsiang; Lee, Chin-jhan; Cheng, Sung-chung; Lin, Hsin-huang |
單位 | 淡江大學化學學系 |
出版者 | Elsevier |
著錄名稱、卷期、頁數 | Inorganic Chemistry Communications 8(3), pp.235-238 |
摘要 | Two new μ-alkoxo-μ-dicarboxylato double bridged tetranuclear copper(II) complexes [Cu4(L-Br)2(μ-C4H4O4)(dmf)2] (1) and [Cu4(L-Cl)2(μ-C4H4O4)(dmf)2] (2) (H3L-Br = 1,3-bis(5-bromo-salicylideneamino)-2-propanol; H3L-Cl = 1,3-bis(5-chloro-salicylideneamino)-2-propanol; dmf = N,N-dimethylformamide) have been prepared and structurally characterized. Temperature dependence of magnetic susceptibility measurements show a ferromagnetic coupling between two copper(II) ions in complex 1 with J = 54 cm−1, and in 2 with J = 56 cm−1. |
關鍵字 | μ-alkoxo-μ-dicarboxylato double bridges;Tetranuclear copper(II) complex;Crystal structure;Magnetic property |
語言 | en |
ISSN | 1387-7003 |
期刊性質 | 國內 |
收錄於 | |
產學合作 | |
通訊作者 | |
審稿制度 | 否 |
國別 | TWN |
公開徵稿 | |
出版型式 | ,電子版 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/24981 ) |