教師資料查詢 | 類別: 期刊論文 | 教師: 余良杰 YU, LIANG-JYE (瀏覽個人網頁)

標題:Highly Conjugated Molecules from Dibromonaphthyl Derivatives and 4-Vinylpyridine or 4-Acetoxystyrene by the Heck Reaction
學年87
學期2
出版(發表)日期1999/07/23
作品名稱Highly Conjugated Molecules from Dibromonaphthyl Derivatives and 4-Vinylpyridine or 4-Acetoxystyrene by the Heck Reaction
作品名稱(其他語言)
著者Chang, C. C.; Chen, K. J.; 余良杰; Yu, L. J.
單位淡江大學化學學系
出版者American Chemical Society (ACS)
著錄名稱、卷期、頁數Journal of Organic Chemistry 64(15), pp.5603-5610
摘要Palladium-catalyzed coupling of 1,6- and 2,6-dibromonaphthyl derivatives with 4-vinylpyridine or 4-acetoxystyrene resulted in mono- and bis-arylvinylation depending on the choice of reaction conditions. For the 1,6-dibromoarenes, the mono-arylvinylated derivative at position-6 was the sole product in the presence of (o-tol)3P/Et3N. The bis-arylvinylated derivative was the major product, accompanied by a minor product, arylvinylated at position-6 and reduced at position-1, in the presence of (o-tol)3P/Et3N/MeCN. For the 2,6-dibromoarenes, the bis-arylvinylated derivative was the sole product in the presence of either Ph3P or (o-tol)3P, if provided with a small volume of Et3N/MeCN solvent, and the mono-arylvinylated derivative was the major product with larger solvent volume and higher haloarene ratio. Fluorescence intensities of 2,6-bis-arylvinylated products were 2 to 3 orders of magnitude higher than that of stilbene. Nematic phases, at relatively high temperatures, were observed for some of the rodlike molecules. Shown by 1H NMR study, at the photostationary state of isomerization, smaller fractions of cis-form were obtained for molecules that exhibited larger fluorescence quantum yields. The results presented here are beneficial to the pursuit of nonlinear optical materials, fluorescent mesogens, photo- and electroactive materials.
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語言英文
ISSN0022-3263
期刊性質國內
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審稿制度
國別中華民國
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