| 標題：Preparative, structural, and physical studies of TTM-TTF complexes with Qmnt a quinone-type acceptor fused with sulfur-containing heterocycles |
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| 學年 | 83 |
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| 學期 | 2 |
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| 出版（發表）日期 | 1995/03/15 |
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| 作品名稱 | Preparative, structural, and physical studies of TTM-TTF complexes with Qmnt a quinone-type acceptor fused with sulfur-containing heterocycles |
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| 作品名稱（其他語言） | Qmnt(一種銜合含硫雜環的Quinono類電子受體)與TTM-TTF之錯合物的製備、結構和物性研究 |
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| 著者 | 李榮熹; Lee, J. S.; Chang, K.; 王文竹; Wang, Wen-jwu; Lee, G. H. |
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| 單位 | 淡江大學化學學系 |
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| 出版者 | Lausanne: Elsevier S.A. |
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| 著錄名稱、卷期、頁數 | Synthetic metals 70(1-3), pp.1221-1222 |
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| 摘要 | The 2:3 complex of tetrakis(methylthio)tetrathiafulvalene (TTM-TTF) and the acceptor 5,10-dihydro-5,1-dioxobenzo- [1,2-b:4,5-b′]bis[1,4]dithiin-2,3,7,8-tetracarbonitrile (Qmnt), a p-benzoquinone derivative fused with sulfur-containing heterocycles, was prepared as powder by mixing equi-molar TTM-TTF and Qmnt in hot acetonitrile. Slow evaporation of dilute acetonitrile solution of [TTM-TTF]2[Qmnt]3 yielded needle-like crystals of [TTM-TTF][Qmnt]. The 1:1 complex crystallizes in the triclinic space group P1, with a=7.114(4),b=10.434(3), c=11.305(3)A, α=106.83(3), β=103.03(3), γ=96.82(3)•, Z=1. The TTM-TTF and Qmnt molecules are stacking alternately along the α axis, with their long molecular axes nearly perpendicular to each other. The room-temperature DC conductivity (compressed pellet) of [TTM-TTF]2[Qmnt]3 is 0.22 S cm−1 with Ea=0.14 eV, and that of [TTM-TTF][Qmnt] is 1.5 × 10−5S cm−1 with Ea=0.36 eV |
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| 關鍵字 | |
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| 語言 | 英文 |
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| ISSN | 0379-6779 |
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| 期刊性質 | 國外 |
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| 產學合作 | |
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| 國別 | 瑞士 |
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| 公開徵稿 | |
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| 出版型式 | 紙本 |
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