| A facile and efficient synthesis of aryltriethoxysilanes via sonochemical Barbier-type reaction | |
|---|---|
| 學年 | 95 | 
| 學期 | 1 | 
| 出版(發表)日期 | 2006-09-25 | 
| 作品名稱 | A facile and efficient synthesis of aryltriethoxysilanes via sonochemical Barbier-type reaction | 
| 作品名稱(其他語言) | |
| 著者 | 李世元; Lee, Adam Shih-yuan; Chang, Y. T.; Chu, S. F.; Tsao, K. W. | 
| 單位 | 淡江大學化學學系 | 
| 出版者 | Elsevier | 
| 著錄名稱、卷期、頁數 | Tetrahedron Letters 47(39), pp.7085-7087 | 
| 摘要 | A series of aryltriethoxysilanes was synthesized from the reaction mixture of aryl bromide, Mg powder, 1,2-dibromoethane and tetraethyl orthosilicate in THF under ultrasound. This sonochemical Barbier-type reaction provides a simple and efficient method for preparation of aryltriethoxysilanes. The Hiyama cross-coupling reaction of phenyltriethoxysilane with bromobenzene was investigated under different palladium catalysts and Pd(PhCN)2Cl2 was found to be the best choice. | 
| 關鍵字 | |
| 語言 | en | 
| ISSN | 0040-4039 | 
| 期刊性質 | 國外 | 
| 收錄於 | |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 | 
| 國別 | GBR | 
| 公開徵稿 | |
| 出版型式 | ,紙本 | 
| 相關連結 | 
                                         機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/24934 )  |