Observation of self-ion-molecule reactions during collisionally activated dissociation in an ion-trap mass spectrometer | |
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學年 | 92 |
學期 | 2 |
出版(發表)日期 | 2004-04-01 |
作品名稱 | Observation of self-ion-molecule reactions during collisionally activated dissociation in an ion-trap mass spectrometer |
作品名稱(其他語言) | |
著者 | Wu, Hui-fen; Wu, Mon-tin; Chen, Chien-hung |
單位 | 淡江大學化學學系 |
出版者 | Chichester: John Wiley & Sons Ltd. |
著錄名稱、卷期、頁數 | Journal of mass spectrometry 39(4), pp.396-401 |
摘要 | This paper describes the formation of protonated molecules ([M + H]+) and adduct ions by self-ion-molecule reactions (SIMR) during collisionally activated decomposition (CAD) of methyne addition ions ([M + CH]+) produced from chemical ionization (CI) or SIMR in both an external and internal source ion-trap mass spectrometer (ITMS). The CAD results for the methyne addition ions of dopamine produced from both SIMR and dimethyl ether CI undertaken in the external and internal source ITMS were compared in order to prove the occurrence of SIMR during CAD processes. Compared with the external source ITMS, the internal source ITMS is much more easily applicable to this type of reaction owing to the large population of neutral analytes present in the trap. |
關鍵字 | ion–molecule reactions; ion trap; dopamine |
語言 | en |
ISSN | 1076-5174 1096-9888 |
期刊性質 | 國外 |
收錄於 | |
產學合作 | |
通訊作者 | |
審稿制度 | |
國別 | GBR |
公開徵稿 | |
出版型式 | 紙本 |
相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25116 ) |