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序號 學年期 教師動態
1 109/1 物理系 彭維鋒 教授 期刊論文 發佈 Structural, electronic, and electrical behaviour of MWCNTs: TiO2 (: SiO2) nanocomposites , [109-1] :Structural, electronic, and electrical behaviour of MWCNTs: TiO2 (: SiO2) nanocomposites期刊論文Structural, electronic, and electrical behaviour of MWCNTs: TiO2 (: SiO2) nanocompositesJames A. Oke, David O. Idisi, Sabata J. Moloi, Sekhar C. Ray*, K.H. Chen, A. Ghosh, A. Shelke, W. F. Pong*Journal of Electron Spectroscopy and Related Phenomena 245, 147002 SCI;否
2 102/2 化材系 董崇民 教授 期刊論文 發佈 Unusual mechanical properties of melt-blended poly(lactic acid) (PLA)/clay nanocomposites, , [102-2] :Unusual mechanical properties of melt-blended poly(lactic acid) (PLA)/clay nanocomposites,期刊論文Unusual mechanical properties of melt-blended poly(lactic acid) (PLA)/clay nanocomposites,Sun-Mou Lai; Sheng-Huang Wu; Gwo-Geng Lin; Trong-Ming DonPoly(lactic acid);Clay;Nanocomposites;Mechanical properties;ExfoliationEuropean Polymer Journal 52, p.193–206The commercial organic-modified clay was incorporated into a nearly amorphous PLA matrix using a melt-blending process to form PLA/clay nanocomposites. The nanocomposite containing 1 phr of clay conferred the highest exfoliation of clay among all investigated clay dosages. Especially, only this particular nanocomposite had a lower modulus and exhibited significant stress-whitening and necking behavior with a large extension, elongation at break being increased to 208%, up to 37-fold increment compared to the neat PLA. Based on SEM and TEM pictures, the highly exfoliated platelets produced a relatively large interfacial area between the clay p
3 108/2 物理系 彭維鋒 教授 期刊論文 發佈 Polyacrylate grafted graphene oxide nanocomposites for biomedical applications , [108-2] :Polyacrylate grafted graphene oxide nanocomposites for biomedical applications期刊論文Polyacrylate grafted graphene oxide nanocomposites for biomedical applicationsElison S. Ganya; Navneet Soin; Sabata J. Moloi; James A. McLaughlin; W. F. Pong; Sekhar C. RayJournal of Applied Physics 127(5), 054302Utilizing a reverse micelle process, we have grafted polyacrylate (P) on graphene oxide (GO) to realize polyacrylate grafted graphene oxide (P-GO) nanocomposites, upon whose subsequent reduction, polyacrylate grafted reduced graphene oxide (P-rGO) nanocomposites are achieved. Using techniques such as ultraviolet photoelectron spectroscopy (UPS), x-ray photoelectron spectroscopy, and x-ray absorption near edge structure (XANES) spectroscopy, in conjunction with high-resolution microscopy, Raman spectroscopy, and superconducting quantum interference device analysis, we have studied in depth the electronic, microstructural, electrical, and magnetic properties of these P-GO and P-rGO nanocomposites.
4 109/1 物理系 彭維鋒 教授 期刊論文 發佈 Tuning the electronic and magnetic properties of PEDOT-PSS-coated graphene oxide nanocomposites for biomedical applications , [109-1] :Tuning the electronic and magnetic properties of PEDOT-PSS-coated graphene oxide nanocomposites for biomedical applications期刊論文Tuning the electronic and magnetic properties of PEDOT-PSS-coated graphene oxide nanocomposites for biomedical applicationsElison S. Ganya; Sabata J. Moloi; Sekhar C. Ray; W. F. PongJournal of Materials Research 35(18), p.2478-2490We have synthesized graphene oxide (GO) using Hummer's method which was subsequently reduced (rGO) by hydrazine hydrate. The synthesized GO was coated with poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT-PSS) conducting polymer (CP) to obtain CP-GO which was also further reduced using hydrazine hydrate to form CP-rGO. Scanning electron microscopy, Raman spectroscopy, X-ray diffraction, ultraviolet photoelectron spectroscopy, and X-ray photoelectron spectroscopy, X-ray absorption near-edge structure (XANES) techniques were used to study the electronic and structural properties of GO, rGO, CP-GO, and CP-rGO nanocomposites
5 109/1 物理系 彭維鋒 教授 期刊論文 發佈 Structural, electronic, and electrical behaviour of MWCNTs: TiO2 (:SiO2) nanocomposites , [109-1] :Structural, electronic, and electrical behaviour of MWCNTs: TiO2 (:SiO2) nanocomposites期刊論文Structural, electronic, and electrical behaviour of MWCNTs: TiO2 (:SiO2) nanocompositesJames A. Oke; David O. Idisi; Sabata J. Moloi; Sekhar C. Ray; K.H. Chen; A. Ghosh; A. Shelke; W. F. PongTiO2;SiO2;MWCNTs;NCs;Raman spectroscopy;XPS I-V techniqueJournal of Electron Spectroscopy and Related Phenomena 245, 147002We have functionalized multiwall carbon nanotubes (MWCNTs) with the composition of SiO2 and TiO2 (MWCNTs:TiO2:SiO2) at different Ti:Si stoichiometric ratios (Ti:Si ≈ 6:6 at% and ≈10:10 at%) using the hydrothermal process. The micro-structural, electronic and electrical properties of the unfunctionalized and functionalized MWCNTs were studied. Changes in surface morphology, degree of hybridization, crystallite structure and bonding structure due to functionalization were studied using field-emission scanning electron microscopy, Raman spectroscopy, x-ray diffraction, x-ray photoemission sp
6 108/1 物理系 彭維鋒 教授 期刊論文 發佈 Tuning of electronic and electrical behaviour of MWCNTs-TiO2 nanocomposites , [108-1] :Tuning of electronic and electrical behaviour of MWCNTs-TiO2 nanocomposites期刊論文Tuning of electronic and electrical behaviour of MWCNTs-TiO2 nanocompositesJames A.Okea; David O. Idisia; Sweety Sarmaa; S. J. Moloi; Sekhar C. Ray; K. H. Chen; A. Ghosh; A. Shelkeb; S.-H. Hsiehc; W. F. PongbTiO2;MWCNTs;MWCNTs-TiO2;Raman spectroscopy;XPS;I-V measurementsDiamond and Related Materials ,Volume 100,論文編號107570The improvement of electronic structure and electrical behaviour of low-density materials have been of great concern. Multiwall carbon nanotube (MWCNT) has been identified as a low-density material, which needs attention to be used mostly as a strengthening phase in lightweight metal lattice composites (MLC). In this work, vaporization and drying process were used to produce TiO2 incorporated MWCNTs nanocomposites. The incorporation of TiO2 is to improve electronic system as well as electrical behaviour of MWCNTs in oxidized atmosphere, which is essential in most of MLC processing methods. W
7 108/1 物理系 彭維鋒 教授 期刊論文 發佈 Electronic, Electrical, and Magnetic Behavioral Change of SiO2-NP-Decorated MWCNTs , [108-1] :Electronic, Electrical, and Magnetic Behavioral Change of SiO2-NP-Decorated MWCNTs期刊論文Electronic, Electrical, and Magnetic Behavioral Change of SiO2-NP-Decorated MWCNTsJames A. Oke; David O. Idisi; Sweety Sarma; Sabata J. Moloi; Sekhar C. Ray; Kuan Hung Chen; Anirudha Ghosh; Abhijeet Shelke; Way Faung PongACS Omega 4(11), p.14589−14598Silicon-oxide-nanoparticle (SiO2-NP) heteroatoms were decorated/deposited onto multiwall carbon nanotube (MWCNT) surface to tune the properties of MWCNTs for electronic and magnetic applications. To achieve this objective, SiO2-NPs and MWCNTs were prepared and suspended together into toluene and heated at <100 °C for the formation of MWCNTs/SiO2-NP nanocomposites. A change in the microstructure, electronic, electrical, and magnetic behaviors of MWCNT nanocomposites decorated/deposited with silicon content was investigated using different techniques, viz., scanning electron microscopy, X-ray diffraction, Raman spectroscopy, and X-ray photoelectron spectros
8 107/2 物理系 董崇禮 副教授 期刊論文 發佈 Au-BINOL Hybrid Nanocatalysts: Insights into the Structure-Based Enhancement of Catalytic and Photocatalytic Performance , [107-2] :Au-BINOL Hybrid Nanocatalysts: Insights into the Structure-Based Enhancement of Catalytic and Photocatalytic Performance期刊論文Au-BINOL Hybrid Nanocatalysts: Insights into the Structure-Based Enhancement of Catalytic and Photocatalytic PerformanceS. R. Patlolla; C. R. Kao; G. W. Chen; Y. C. Huang; Y. C. Chuang; B. T. Sneed; W. C. Chou; T. G. Ong; C. L. Dong; C. H. KuoIndustrial & Engineering Chemistry Research 58(14), p.5479–5489Advances in new systems of organic–inorganic hybrid nanocomposites are less prevalent, owing to a lack of facile strategies for precise control of their structures, compositions, and, hence, their properties. In this work, Au-BINOL hybrid nanocomposites with eccentric and concentric nanostructures were produced. The hybrid nanocomposites containing two distinct moieties of inorganic Au nanocrystals and organic BINOL nanospheres were applied to the catalytic hydrogenation of 4-nitrophenol with NaBH4 in the aqueous phase with and without the illumination of visible
9 107/2 化材系 董崇民 教授 期刊論文 發佈 Preparation of transparent nanocomposites from UV- and thermo-curable epoxyacrylate and graphene oxide for the application of corrosion protection coatings , [107-2] :Preparation of transparent nanocomposites from UV- and thermo-curable epoxyacrylate and graphene oxide for the application of corrosion protection coatings期刊論文Preparation of transparent nanocomposites from UV- and thermo-curable epoxyacrylate and graphene oxide for the application of corrosion protection coatingsCian-Fan Syu; Yen-Ting Lin; Yih-Chang Yeh; Trong-Ming Donepoxyacrylate;graphene oxide;corrosion protection hardness;transparencyPolymer International 68(10), p.1804-1816In this study, we report UV‐ and thermo‐curable epoxyacrylate/graphene oxide (EA/GO) nanocomposites that present good transparency, excellent pencil hardness and promising improvement in corrosion protection. A dual‐curable EA oligomer with one terminal epoxide and one double bond at the other end was synthesized by reaction of diglycidyl ether of bisphenol‐A and acrylic acid. After mixing EA and GO with the curing agents and reactive diluent followed by UV cure and thermo‐cure, the resulting EA/GO films on a gl
10 107/2 物理系 彭維鋒 教授 期刊論文 發佈 Electronic, electrical and magnetic behaviours of reduced graphene-oxide functionalized with silica coated gold nanoparticles , [107-2] :Electronic, electrical and magnetic behaviours of reduced graphene-oxide functionalized with silica coated gold nanoparticles期刊論文Electronic, electrical and magnetic behaviours of reduced graphene-oxide functionalized with silica coated gold nanoparticlesPong, W.F.R-GO;R-GO:Au-NPs;XANES;XPS;M-H;I-VApplied Surface Science 483, p.106-113We have synthesized graphene-oxide (GO) by the modified hummer's process and subsequently reduced it with gold-nanoparticles (Au-NPs) using silica coated colloidal Au-NPs and hydrazine monohydrate solutions to form r-GO:Au-NPs nanocomposites. We have studied the microstructure, electronic, electrical and magnetic properties of r-GO and r-GO:Au-NPs nanocomposites. We have observed from the Raman spectroscopy that the intensity of D-peak (disorder) gets reduced with respect to G (graphite-cluster) in r-GO:Au-NPs composites. The reduction of ID/IG ratio obtained from Raman spectra [r-GO: 1.22 → r-GO:(Au-NPs)4.88: 0.98] clearly indicates that the sp2-cluster i
11 107/2 物理系 彭維鋒 教授 期刊論文 發佈 Tuning of electronic and magnetic properties of multifunctional r-GO-ATA-Fe2O3-composites for magnetic resonance imaging (MRI) contrast agent , [107-2] :Tuning of electronic and magnetic properties of multifunctional r-GO-ATA-Fe2O3-composites for magnetic resonance imaging (MRI) contrast agent期刊論文Tuning of electronic and magnetic properties of multifunctional r-GO-ATA-Fe2O3-composites for magnetic resonance imaging (MRI) contrast agentPong, W.F.Journal of Applied Physics 126, p.035301We have synthesized r-GO-ATA-Fe2O3 nanocomposites and studied their microstructural and electromagnetic properties for future possible magnetic resonance imaging for biomedical application. X-ray diffraction, transmission electron microscopy, Raman spectroscopy, X-ray photoelectron spectroscopy, and X-ray absorption near edge spectroscopy were used to study the structural and electronic properties, while a superconducting quantum interface device magnetometer was used for investigating the magnetic behavior of the nanocomposites. The nanocomposites have been found to reduce the graphitic structure of GO due to the substitution of carbon/oxygen and/or iron
12 104/2 物理系 董崇禮 副教授 期刊論文 發佈 Electrochemical and in situ X-ray spectroscopic studies of MnO2/reduced graphene oxide nanocomposites as a supercapacitor , [104-2] :Electrochemical and in situ X-ray spectroscopic studies of MnO2/reduced graphene oxide nanocomposites as a supercapacitor期刊論文Electrochemical and in situ X-ray spectroscopic studies of MnO2/reduced graphene oxide nanocomposites as a supercapacitorH. W. Chang; Y. R. Lu; J. L. Chen; C. L. Chen; J. F. Lee; J. M. Chen; Y. C. Tsai; P. H. Yeh; W. C. Chou; C. L. DongPhysical Chemistry Chemical Physics 18, p.18705-18718Electrochemical and in situ X-ray absorption spectroscopy (XAS) measurements of various MnO2-coated carbon materials (MnO2/acid-functionalized carbon nanotubes (C-CNT), MnO2/reduced graphene oxide (RGO), and MnO2/RGO-Au electrodes) were conducted to evaluate the supercapacitive performances and electronic structures. MnO2 was deposited on the surface of C-CNT, RGO, and RGO-Au via a spontaneous redox reaction to facilitate the growth of the bulk form of MnO2/C-CNT and the surface forms of MnO2/RGO-based materials. Various forms of MnO2 on the carbon materials exhibited different c
13 104/2 物理系 董崇禮 副教授 期刊論文 發佈 Electrochemical and in situ X-ray spectroscopic studies of MnO2/reduced graphene oxide nanocomposites as a supercapacitor , [104-2] :Electrochemical and in situ X-ray spectroscopic studies of MnO2/reduced graphene oxide nanocomposites as a supercapacitor期刊論文Electrochemical and in situ X-ray spectroscopic studies of MnO2/reduced graphene oxide nanocomposites as a supercapacitorHan-Wei Chang; Ying-Rui Lu; Jeng-Lung Chen; Chi-Liang Chen; Jyh-Fu Lee; Jin-Ming Chen; Yu-Chen Tsai; Ping-Hung Yeh; Wu Ching Chou; Chung-Li DongPhysical Chemistry Chemical Physics 18(28), p.18705-18718Electrochemical and in situ X-ray absorption spectroscopy (XAS) measurements of various MnO2-coated carbon materials (MnO2/acid-functionalized carbon nanotubes (C-CNT), MnO2/reduced graphene oxide (RGO), and MnO2/RGO-Au electrodes) were conducted to evaluate the supercapacitive performances and electronic structures. MnO2 was deposited on the surface of C-CNT, RGO, and RGO-Au via a spontaneous redox reaction to facilitate the growth of the bulk form of MnO2/C-CNT and the surface forms of MnO2/RGO-based materials. Various forms of MnO2 on the carbo
14 104/2 化材系 林正嵐 教授 期刊論文 發佈 Enhancement of electroactivity of platinum-tungsten trioxide nanocomposites with NaOH-treated carbon support toward methanol oxidation reaction , [104-2] :Enhancement of electroactivity of platinum-tungsten trioxide nanocomposites with NaOH-treated carbon support toward methanol oxidation reaction期刊論文Enhancement of electroactivity of platinum-tungsten trioxide nanocomposites with NaOH-treated carbon support toward methanol oxidation reactionCheng-Lan Lin; Chih-Chung WangElectrocatalyst;Methanol oxidation reaction;Nanocomposite;Tungsten trioxideApplied Energy 164, P1043-1051Platinum–tungsten trioxide nanocomposite electrocatalysts on carbon black support (Pt–WO3/C) are synthesized and their electrocatalytic performances toward methanol oxidation reaction (MOR) are investigated in this study. Tungsten trioxide, which derived from the hydrolysis of tungsten hexachloride (WCl6) in dimethylformamide (DMF) solution, is firstly deposited onto pristine or NaOH-treated Vulcan XC-72 carbon black (C or Cs) support to obtain tungsten trioxide/carbon black (WO3/C or WO3/Cs) nanocomposites, and then Pt nanoparticles are decorated onto these nanocompos
15 104/2 化材系 黃招財 副教授 期刊論文 發佈 Melt Creep Recovery of Polyamide 6 and Polypropylene Nanocomposites Blended with Layered Silicate , [104-2] :Melt Creep Recovery of Polyamide 6 and Polypropylene Nanocomposites Blended with Layered Silicate期刊論文Melt Creep Recovery of Polyamide 6 and Polypropylene Nanocomposites Blended with Layered SilicateLin, G. G.; Jian, Y. F. Jang; Huang, C. T.International Polymer Processing 31(1), p.11-17Nanocomposites of polyamide six (PA6) reinforced with organoclay were prepared in this study through melt mixing. The blended montmorillonite clay was organically modified with octadecylamine. The loadings of the clay were 1 wt%, 5 wt%, and 9 wt%. The obtained nanocomposites exhibited exfoliation (1 wt%) and intercalation (other compositions) structures. By contrast, if they were mixed with unmodified clay, the PA6 molecules could not enter the silicate interlayer. For polypropylene (PP), forming nanocomposites with organoclay was difficult but made feasible by incorporating the maleated PP. The results of dynamic rheological tests demonstrated that an end-tethered storage modulus was observed for the PA
16 100/1 機電系 林清彬 教授 期刊論文 發佈 Fabrication microstructural analysis, and properties of poly(methyl methacrylate)/calcium carbonate particulates nanocomposites. , [100-1] :Fabrication microstructural analysis, and properties of poly(methyl methacrylate)/calcium carbonate particulates nanocomposites.期刊論文Fabrication microstructural analysis, and properties of poly(methyl methacrylate)/calcium carbonate particulates nanocomposites.Chang, Z.C.; Lin, C.B.; Chou, Y.-C.; Lee, H.-C.gas-synthesis;glass transition;microstructure;Nanocomposites;Poly(methyl methacrylate)Advances in Polymer Technology 31(4), pp.280-291The poly(methyl methacrylate) (PMMA)/nanometer-scaled calcium carbonate particulate nanocomposites prepared by means of the gas-synthesis was investigated. PMMA absorbed the saturated solvent mixture (the ratio of calcium chloride dehydrate and methanol at 1.5, 4.5, and 6.0 g/100 g) at 40–60° and then desorbed the methanol completely and then CO2 gas diffused into the desorbed completely in specimens for 48 h at 60°, approximately 30-nm calcium carbonate particulates were precipitated evenly to distribute in the PMMA matrix. The content of calcium carbo
17 104/2 化材系 林國賡 教授 期刊論文 發佈 Melt Creep Recovery of Polyamide 6 and Polypropylene Nanocomposites Blended with Layered Silicate , [104-2] :Melt Creep Recovery of Polyamide 6 and Polypropylene Nanocomposites Blended with Layered Silicate期刊論文Melt Creep Recovery of Polyamide 6 and Polypropylene Nanocomposites Blended with Layered SilicateG.-G. Lin; Y.-F. Jang Jian; C.-T. HuangClay;Creep;Nanocomposites;Polyamides;RheologyInternational Polymer Processing 31(1), pp.11-17Nanocomposites of polyamide six (PA6) reinforced with organoclay were prepared in this study through melt mixing. The blended montmorillonite clay was organically modified with octadecylamine. The loadings of the clay were 1 wt%, 5 wt%, and 9 wt%. The obtained nanocomposites exhibited exfoliation (1 wt%) and intercalation (other compositions) structures. By contrast, if they were mixed with unmodified clay, the PA6 molecules could not enter the silicate interlayer. For polypropylene (PP), forming nanocomposites with organoclay was difficult but made feasible by incorporating the maleated PP. The results of dynamic rheological tests demonstrated that an end-tethe
18 104/1 化材系 林國賡 教授 期刊論文 發佈 Isobutylene-isoprene rubber/layered silicate nanocomposites prepared using latex method: Direct casting versus melt mixing after coagulation , [104-1] :Isobutylene-isoprene rubber/layered silicate nanocomposites prepared using latex method: Direct casting versus melt mixing after coagulation期刊論文Isobutylene-isoprene rubber/layered silicate nanocomposites prepared using latex method: Direct casting versus melt mixing after coagulationChiz -Cheng Chao; Gwo-Geng Lin; Hsieh-Chih Tsai; Po-Hsun Chang; Wen-Tung Cheng; Ging-Ho HsiueIsobutylene;isoprene;rubber;latex;nanocomposites;layer;silicatesJournal of Reinforced Plastics and Composites 34(21), pp.1791-1803In this study, polymer nanocomposites of isobutylene–isoprene rubber blended with sodium–montmorillonite were prepared using latex and co-coagulating methods and their influence on thermal, mechanical, and gas barrier if isobutylene–isoprene rubber composites were compared. The dispersion of the layered silicates in the matrix of the obtained nanocomposites was investigated using transmission electron microscopy and X-ray diffraction. The transmission electron microscopy images revealed b
19 103/1 安全衛生小組 董崇民 教授 期刊論文 發佈 Flammability and tensile properties of polylactide nanocomposites with short carbon fibers , [103-1] :Flammability and tensile properties of polylactide nanocomposites with short carbon fibers期刊論文Flammability and tensile properties of polylactide nanocomposites with short carbon fibersCheng; K.-C.; Lin; Y.-H.; Guo; W.; Chuang; T.-H.; Chang; S.-C.; Wang; S.-F.; Don; T.-M.Journal of Materials Science 50(4), pp 1605-1612.Nanocomposites of polylactide (PLA) with aluminum hydroxide (ATH), short carbon fibers (CF), and montmorillonite (MMT) were prepared via direct melt blending. The exfoliated and intercalated clay structures with some aggregations in the PLA matrix were observed. The tensile strength and elongation at break of the PLA composite caused by the high content of the retardant ATH were improved by adding modified MMT and CF to replace a portion of ATH in the PLA matrix. The thermal degradation temperatures and char residue of the PLA/ATH/MMT/CF nanocomposites as determined by thermogravimetric analysis were higher than without MMT. Furthermore, a novel method was proposed to ana
20 102/2 化材系 董崇民 教授 期刊論文 發佈 Unusual mechanical properties of melt-blended poly(lactic acid) (PLA)/clay nanocomposites , [102-2] :Unusual mechanical properties of melt-blended poly(lactic acid) (PLA)/clay nanocomposites期刊論文Unusual mechanical properties of melt-blended poly(lactic acid) (PLA)/clay nanocompositesLai, Sun-Mou; Wu,Sheng-Huang; Lin, Gwo-Geng; Don, Trong-Ming淡江大學化學工程與材料工程學系Poly(lactic acid);Clay;Nanocomposites;Mechanical properties;ExfoliationKidlington: PergamonEuropean Polymer Journal 52, pp.193–206The commercial organic-modified clay was incorporated into a nearly amorphous PLA matrix using a melt-blending process to form PLA/clay nanocomposites. The nanocomposite containing 1 phr of clay conferred the highest exfoliation of clay among all investigated clay dosages. Especially, only this particular nanocomposite had a lower modulus and exhibited significant stress-whitening and necking behavior with a large extension, elongation at break being increased to 208%, up to 37-fold increment compared to the neat PLA. Based on SEM and TEM pictures, the highly exfoliated platelets produced a relatively larg
21 102/2 化材系 林國賡 教授 期刊論文 發佈 Unusual mechanical properties of melt-blended poly(lactic acid) (PLA)/clay nanocomposites , [102-2] :Unusual mechanical properties of melt-blended poly(lactic acid) (PLA)/clay nanocomposites期刊論文Unusual mechanical properties of melt-blended poly(lactic acid) (PLA)/clay nanocompositesLai, Sun-Mou; Wu,Sheng-Huang; Lin, Gwo-Geng; Don, Trong-Ming淡江大學化學工程與材料工程學系Poly(lactic acid);Clay;Nanocomposites;Mechanical properties;ExfoliationKidlington: PergamonEuropean Polymer Journal 52, pp.193–206The commercial organic-modified clay was incorporated into a nearly amorphous PLA matrix using a melt-blending process to form PLA/clay nanocomposites. The nanocomposite containing 1 phr of clay conferred the highest exfoliation of clay among all investigated clay dosages. Especially, only this particular nanocomposite had a lower modulus and exhibited significant stress-whitening and necking behavior with a large extension, elongation at break being increased to 208%, up to 37-fold increment compared to the neat PLA. Based on SEM and TEM pictures, the highly exfoliated platelets produced a relatively larg
22 103/1 化材系 許世杰 副教授 期刊論文 發佈 Enhancing the insulation of wide-range spectrum in the PVA/N thin film by doping ZnO nanowires , [103-1] :Enhancing the insulation of wide-range spectrum in the PVA/N thin film by doping ZnO nanowires期刊論文Enhancing the insulation of wide-range spectrum in the PVA/N thin film by doping ZnO nanowiresiang-Yih Chen; ShihYu-Chen Lin; Ching-Hsiang Chen; L-Chieh Hsu; Shizhi Qianf化學工程與材料工程學系暨研究所RSC Advances 4(85), pp.45419-45424In this study, polyvinyl alcohol/nitrogen (PVA/N) hybrid thin films doped with sharp-sword ZnO nanowires with insulating effect and wide-range spectrum are demonstrated for the first time. PVA/N doped ZnO nanocomposites were developed by blending PVA and N-doped ZnO nanowires in water at room temperature. Measurements from the field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), Raman, and photoluminescence emission (PL) spectra of the products show that nitrogen is successfully doped into the ZnO wurtzite crystal lattice. In addition, the refractive index of PVA/N doped ZnO hybrid thin films can be controlled by varying the doped ZnO nanowire
23 102/2 化材系 林正嵐 教授 期刊論文 發佈 Platinum nanoparticles supported on zirconia–carbon black nanocomposites for methanol oxidation reaction , [102-2] :Platinum nanoparticles supported on zirconia–carbon black nanocomposites for methanol oxidation reaction期刊論文Platinum nanoparticles supported on zirconia–carbon black nanocomposites for methanol oxidation reactionLin, Cheng-Lan; Yeh, Yu-Chi淡江大學化學工程與材料工程學系Methanol oxidation reaction;Electrocatalyst;Platinum;ZirconiaNetherlands: Springer NetherlandsResearch on Chemical Intermediates 40(6), pp.2207-2215Platinum (Pt) nanoparticles supported on zirconia–carbon black nanocomposites (Zr–C), which annealed at different temperatures, used as Pt/Zr–C electrocatalysts for methanol oxidation reaction (MOR) are prepared and characterized in this study. Transmission electron microscope images and X-ray diffraction analysis showed that the diameters of Pt nanoparticles are around 3–4 nm. Electrocatalytic MOR performances of these Pt/Zr–C electrocatalysts are investigated by cyclic voltammetry, CO-stripping voltammetry, and chronoamperometry. All the Pt/Zr–C electrocatalysts synthesized in this study e
24 93/1 化材系 黃國楨 教授 期刊論文 發佈 Preparation of silica filled poly(2-hydroxymethyl methacrylate) nanocomposites cured by photoirradiation during sol-gel process , [93-1] :Preparation of silica filled poly(2-hydroxymethyl methacrylate) nanocomposites cured by photoirradiation during sol-gel process期刊論文Preparation of silica filled poly(2-hydroxymethyl methacrylate) nanocomposites cured by photoirradiation during sol-gel processLin, Dar-jong; Chen, Ching-chung; Su, Yi-che; Huang, Shu-hui; Cheng, Liao-ping淡江大學化學工程與材料工程學系Journal of applied polymer science 94(5), pp.1927-1935tku_id: 000062592; 000094910;Submitted by 曉芬 游 (139570@mail.tku.edu.tw) on 2011-10-23T16:57:42Z No. of bitstreams: 0;Made available in DSpace on 2011-10-23T16:57:44Z (GMT). No. of bitstreams: 0en國外SCI;EI;否USA<links><record><name>機構典藏連結</name><url>http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/71205</url></record></links>
25 94/2 化材系 黃國楨 教授 期刊論文 發佈 Preparation of Clay/PMMA Nanocomposites with Intercalated or Exfoliated Structure for Bone Cement Synthesis , [94-2] :Preparation of Clay/PMMA Nanocomposites with Intercalated or Exfoliated Structure for Bone Cement Synthesis期刊論文Preparation of Clay/PMMA Nanocomposites with Intercalated or Exfoliated Structure for Bone Cement SynthesisWang, Jyh-horng; Young, Tai-horng; Lin, Dar-jong; Sun, Min-kuei; Huag, Han-shiang; Cheng, Liao-ping淡江大學化學工程與材料工程學系Macromolecular Materials Engineering 291, pp.661-669tku_id: ; 000062592; 000094910;Submitted by 曉芬 游 (139570@mail.tku.edu.tw) on 2011-10-23T16:57:00Z No. of bitstreams: 0;Made available in DSpace on 2011-10-23T16:57:02Z (GMT). No. of bitstreams: 0en國外SCI;EI;否DEU<links><record><name>機構典藏連結</name><url>http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/71191</url></record></links>
26 100/1 機電系 林清彬 教授 期刊論文 發佈 Fabrication, microstructural analysis, and properties of poly(methyl methacrylate)/calcium carbonate particulates nanocomposites , [100-1] :Fabrication, microstructural analysis, and properties of poly(methyl methacrylate)/calcium carbonate particulates nanocomposites期刊論文Fabrication, microstructural analysis, and properties of poly(methyl methacrylate)/calcium carbonate particulates nanocompositesChang, Z.C.; Lin, C.B.; Chou, Yi-Chun; Lee, Hung-Chou淡江大學機械與機電工程學系gas-synthesis; glass transition; microstructure; Nanocomposites; Poly(methyl methacrylate)Hoboken: John Wiley & Sons, Inc.Advances in Polymer Technology 31(4), pp.280–291The poly(methyl methacrylate) (PMMA)/nanometer-scaled calcium carbonate particulate nanocomposites prepared by means of the gas-synthesis was investigated. PMMA absorbed the saturated solvent mixture (the ratio of calcium chloride dehydrate and methanol at 1.5, 4.5, and 6.0 g/100 g) at 40–60° and then desorbed the methanol completely and then CO2 gas diffused into the desorbed completely in specimens for 48 h at 60°, approximately 30-nm calcium carbonate particulates were precipitated evenly to dist
27 98/2 化學系 葉正濤 教授 期刊論文 發佈 Effect of weak reductant on properties of electroless copper polyacrylonitrile nanocomposites for electromagnetic interference shielding , [98-2] :Effect of weak reductant on properties of electroless copper polyacrylonitrile nanocomposites for electromagnetic interference shielding期刊論文Effect of weak reductant on properties of electroless copper polyacrylonitrile nanocomposites for electromagnetic interference shieldingTsao, Keng-Yu; Chen, Chang-Cheng; Huang, Chi-Yuan; Tsai, Ching-Shan; Yang, Sung-Yeng; Yeh, Jen-Taut; Chen , Kan-Nan淡江大學化學學系EMI;electroless;CuS;polyacrylonitrileHoboken: John Wiley & Sons, Inc.Journal of Applied Polymer Science 118(2), pp. 936-942In this work, the electroless copper method with different reductant compositions (NaHSO3/Na2 S2O3·5H2O and Na2S2O3·5H2O) without sensitizing and activating, was used to deposit copper-sulfide deposition on the polyacrylonitrile (PAN) surface for electromagnetic interference (EMI) shielding materials. The weak reductant, NaHSO3, in the electroless copper method was used to control the phase of copper-sulfide deposition. The Cux(x=1–1.8)S was deposited on the PAN (CuxS-PAN)
28 98/2 化材系 陳幹男 教授 期刊論文 發佈 Effect of weak reductant on properties of electroless copper polyacrylonitrile nanocomposites for electromagnetic interference shielding , [98-2] :Effect of weak reductant on properties of electroless copper polyacrylonitrile nanocomposites for electromagnetic interference shielding期刊論文Effect of weak reductant on properties of electroless copper polyacrylonitrile nanocomposites for electromagnetic interference shieldingTsao, Keng-Yu; Chen, Chang-Cheng; Huang, Chi-Yuan; Tsai, Ching-Shan; Yang, Sung-Yeng; Yeh, Jen-Taut; Chen , Kan-Nan淡江大學化學學系EMI;electroless;CuS;polyacrylonitrileHoboken: John Wiley & Sons, Inc.Journal of Applied Polymer Science 118(2), pp. 936-942In this work, the electroless copper method with different reductant compositions (NaHSO3/Na2 S2O3·5H2O and Na2S2O3·5H2O) without sensitizing and activating, was used to deposit copper-sulfide deposition on the polyacrylonitrile (PAN) surface for electromagnetic interference (EMI) shielding materials. The weak reductant, NaHSO3, in the electroless copper method was used to control the phase of copper-sulfide deposition. The Cux(x=1–1.8)S was deposited on the PAN (CuxS-PAN)
29 98/1 化材系 陳幹男 教授 期刊論文 發佈 The copper sulfide coating on polyacrylonitrile with a chelating agent of ethylenediaminetetraacetic acid by an electroless deposition method and its EMI shielding effectiveness , [98-1] :The copper sulfide coating on polyacrylonitrile with a chelating agent of ethylenediaminetetraacetic acid by an electroless deposition method and its EMI shielding effectiveness期刊論文The copper sulfide coating on polyacrylonitrile with a chelating agent of ethylenediaminetetraacetic acid by an electroless deposition method and its EMI shielding effectivenessChen, Yen-Hung; Huang, Chi-Yuan; Roan, Ming-Lih; Lai, Fu-Der; Chen, Kan-Nan; Yeh, Jen-Taut淡江大學化學學系films; nanocomposites; swelling;copper sulfide; electroless; PANHoboken: John Wiley & Sons, Inc.Journal of Applied Polymer Science 115(1), pp.570–578In this study, a copper sulfide layer was instantaneously coated on the polyacrylonitrile (PAN) by an electroless plating method with the reduction agents NaHSO3 and Na2S2O3·5H2O and a chelating agent (ethylenediaminetetraacetic acid, EDTA). A variety of concentrations of EDTA was added to obtain the anchoring effect and chelating effect in the electroless plating bath. The mechanism of the C
30 93/1 化材系 鄭廖平 教授 期刊論文 發佈 Preparation of silica filled poly(2-hydroxymethyl methacrylate) nanocomposites cured by photoirradiation during sol-gel process , [93-1] :Preparation of silica filled poly(2-hydroxymethyl methacrylate) nanocomposites cured by photoirradiation during sol-gel process期刊論文Preparation of silica filled poly(2-hydroxymethyl methacrylate) nanocomposites cured by photoirradiation during sol-gel processLin, Dar-jong; Chen, Ching-chung; Su, Yi-che; Huang, Shu-hui; Cheng, Liao-ping淡江大學化學工程與材料工程學系Journal of applied polymer science 94(5), pp.1927-1935tku_id: 000062592; 000094910;Submitted by 曉芬 游 (139570@mail.tku.edu.tw) on 2011-10-23T16:57:42Z No. of bitstreams: 0;Made available in DSpace on 2011-10-23T16:57:44Z (GMT). No. of bitstreams: 0en國外SCI;EI;否USA<links><record><name>機構典藏連結</name><url>http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/71205</url></record></links>
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