期刊論文
| 學年 | 115 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2026-09-29 |
| 作品名稱 | Electrochemical Phosphorus Recovery as a Continuum: Integrating Electro-Oxidation, Electrodissolution, and Interfacial Crystallization |
| 作品名稱（其他語言） | |
| 著者 | Jui-Shuan Yu; Vinh Ya; Naresh Mameda |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | Water 18(19) , p.2418 |
| 摘要 | Electrochemical phosphorus recovery (EPR) provides a sustainable alternative to conventional chemical precipitation by generating in situ alkalinity, oxidants, and coagulating cations, thereby minimizing chemical reagent dosing. However, practical implementation remains constrained because electrochemical oxidation (EO), electrodissolution (ED), and electrochemical crystallization are predominantly investigated as separate unit processes, obscuring their synergistic mechanisms. Here, we introduce the Electrochemical Phosphorus Recovery Continuum (EPRC), an integrated mechanistic framework that combines non-orthophosphate activation, Faradaic cation dosing, and interfacial crystallization into a continuous, value-oriented recovery pathway. We systematically review the charge-transfer kinetics, electrode materials, and reactor hydrodynamic architectures governing each stage, while assessing key technical and economic barriers, including specific energy consumption, sacrificial-anode passivation, and matrix-induced competitive-ion effects. Building on this synthesis, we propose an engineering roadmap for scalable, intelligent EPR platforms that convert complex waste streams into customized agricultural fertilizers and high-value phosphate precursors, including FePO4 for potential LiFePO4 synthesis. |
| 關鍵字 | electro-oxidation; electrochemical dissolution; electrocrystallization; non-orthophosphate mineralization; phosphorus recovery; sacrificial anode |
| 語言 | en |
| ISSN | |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | VINH YA, Naresh Mameda |
| 審稿制度 | 否 |
| 國別 | CHE |
| 公開徵稿 | |
| 出版型式 | ,電子版 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/129944 ) |