期刊論文
| 學年 | 114 |
|---|---|
| 學期 | 1 |
| 出版（發表）日期 | 2025-11-25 |
| 作品名稱 | Fe, P Heteronuclear Catalytic Pairs with Hydrogen Bonding Regulated the Oxygen Reduction Reaction Kinetics for an Ultrastable Oxygen Depolarized Cathode |
| 作品名稱（其他語言） | |
| 著者 | Fenghong Lu; Yuanyuan Zhang; Lingbo Zong; Chengbin Wang; Kaicai Fan; Cheng-Hao Chuang; Porun Liu; Zumin Wang; Lei Wang; Bin Li |
| 單位 | |
| 出版者 | |
| 著錄名稱、卷期、頁數 | ACS Nano 19(46), p.40128-40139 |
| 摘要 | The rational design of efficient oxygen reduction reaction (ORR) catalysts with maximized atom utilization is essential for advancing the oxygen depolarized cathode technology. Here, we report atomically dispersed Fe, P heteronuclear catalytic pairs on hierarchical porous carbon, in which the hydrogen bond between Fe, P catalytic pairs and ORR intermediates significantly enhances the adsorption/desorption kinetics and lowers the rate-determining step barrier of OH* desorption. Thus, Fe,P/HPC delivers an alkaline ORR performance with a half-wave potential (E1/2) of 0.92 V and retains ∼90% of the initial activity even after 150 h operation. In addition, Fe,P/HPC achieves an E1/2 of 0.74 V in 0.1 M HClO4. The Fe,P/HPC-based aqueous Zn–air battery (A-ZAB) achieves a high power density of 262 mW cm–2 and exhibits enhanced stability, sustaining a minimal voltage gap over 2800 h of constant-current cycling. Moreover, the quasi-solid-state Zn–air battery (QSS-ZAB) delivers a large open-circuit voltage of 1.52 V, while maintaining a cycling stability for over 95 h at 0.5, 1, and 2 mA cm–2, respectively. In the chlor-alkali process, the Fe,P/HPC||RuO2 electrolyzer enables a large current density of 300 mA cm–2 at 1.66 V and maintains stability over 110 h. The present work pioneers the designing and construction of atomic-level heteronuclear catalysts for practical and durable cathode. |
| 關鍵字 | Zn−air battery; chlor-alkali electrolyzer; heteronuclear catalytic pairs; hierarchical porous structure; hydrogen bonding; oxygen reduction reaction |
| 語言 | en |
| ISSN | 1936-0851; 1936-086X |
| 期刊性質 | 國外 |
| 收錄於 | SCI |
| 產學合作 | |
| 通訊作者 | |
| 審稿制度 | 否 |
| 國別 | USA |
| 公開徵稿 | |
| 出版型式 | ,電子版,紙本 |
| 相關連結 |
機構典藏連結 ( http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/129586 ) |